Dichlorido{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc(II)

In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N′,N′′-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An int...

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Autores principales: Ikmal Hisham, Nurul Azimah, Suleiman Gwaram, Nura, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050202/
https://www.ncbi.nlm.nih.gov/pubmed/21522573
http://dx.doi.org/10.1107/S1600536810050671
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author Ikmal Hisham, Nurul Azimah
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Ikmal Hisham, Nurul Azimah
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Ikmal Hisham, Nurul Azimah
collection PubMed
description In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N′,N′′-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra­molecular C—H⋯Cl inter­action occurs. In the crystal, adjacent mol­ecules are linked together via C—H⋯Cl hydrogen-bonding and long range C—H⋯O and C—H⋯Cl inter­actions into a three-dimensional network.
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spelling pubmed-30502022011-04-26 Dichlorido{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc(II) Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N′,N′′-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra­molecular C—H⋯Cl inter­action occurs. In the crystal, adjacent mol­ecules are linked together via C—H⋯Cl hydrogen-bonding and long range C—H⋯O and C—H⋯Cl inter­actions into a three-dimensional network. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050202/ /pubmed/21522573 http://dx.doi.org/10.1107/S1600536810050671 Text en © Ikmal Hisham et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ikmal Hisham, Nurul Azimah
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
Dichlorido{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc(II)
title Dichlorido{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc(II)
title_full Dichlorido{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc(II)
title_fullStr Dichlorido{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc(II)
title_full_unstemmed Dichlorido{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc(II)
title_short Dichlorido{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc(II)
title_sort dichlorido{2-morpholino-n-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) n,n′,n′′}zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050202/
https://www.ncbi.nlm.nih.gov/pubmed/21522573
http://dx.doi.org/10.1107/S1600536810050671
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AT khaledihamid dichlorido2morpholinon12pyridylethylideneethanaminek3nnnzincii
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