Dicarbonyl­chlorido(phen­oxy­thio­carbonyl-κ(2) C,S)bis­(triphenyl­phosphane-κP)molybdenum(II)

In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octa­hedron. The phen­oxy­thio­carbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π–π inter­molecular inter­actions and a supra...

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Detalles Bibliográficos
Autores principales: Lee, Gene-Hsiang, Wang, Hsiao-Fen, Yih, Kuang-Hway, Huang, Shou-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050204/
https://www.ncbi.nlm.nih.gov/pubmed/21522529
http://dx.doi.org/10.1107/S1600536810052530
Descripción
Sumario:In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octa­hedron. The phen­oxy­thio­carbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π–π inter­molecular inter­actions and a supra­molecular aggregation is determined by inter­molecular C—H⋯O, C—H⋯Cl, C—H⋯π(arene) hydrogen bonds and CO⋯π(arene) inter­actions [O⋯centroid distances = 3.485 (4) and 3.722 (3) Å].

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