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Dicarbonylchlorido(phenoxythiocarbonyl-κ(2) C,S)bis(triphenylphosphane-κP)molybdenum(II)
In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octahedron. The phenoxythiocarbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π–π intermolecular interactions and a supra...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050204/ https://www.ncbi.nlm.nih.gov/pubmed/21522529 http://dx.doi.org/10.1107/S1600536810052530 |
| _version_ | 1782199309014401024 |
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| author | Lee, Gene-Hsiang Wang, Hsiao-Fen Yih, Kuang-Hway Huang, Shou-Ling |
| author_facet | Lee, Gene-Hsiang Wang, Hsiao-Fen Yih, Kuang-Hway Huang, Shou-Ling |
| author_sort | Lee, Gene-Hsiang |
| collection | PubMed |
| description | In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octahedron. The phenoxythiocarbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π–π intermolecular interactions and a supramolecular aggregation is determined by intermolecular C—H⋯O, C—H⋯Cl, C—H⋯π(arene) hydrogen bonds and CO⋯π(arene) interactions [O⋯centroid distances = 3.485 (4) and 3.722 (3) Å]. |
| format | Text |
| id | pubmed-3050204 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30502042011-04-26 Dicarbonylchlorido(phenoxythiocarbonyl-κ(2) C,S)bis(triphenylphosphane-κP)molybdenum(II) Lee, Gene-Hsiang Wang, Hsiao-Fen Yih, Kuang-Hway Huang, Shou-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octahedron. The phenoxythiocarbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π–π intermolecular interactions and a supramolecular aggregation is determined by intermolecular C—H⋯O, C—H⋯Cl, C—H⋯π(arene) hydrogen bonds and CO⋯π(arene) interactions [O⋯centroid distances = 3.485 (4) and 3.722 (3) Å]. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050204/ /pubmed/21522529 http://dx.doi.org/10.1107/S1600536810052530 Text en © Lee et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lee, Gene-Hsiang Wang, Hsiao-Fen Yih, Kuang-Hway Huang, Shou-Ling Dicarbonylchlorido(phenoxythiocarbonyl-κ(2) C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title | Dicarbonylchlorido(phenoxythiocarbonyl-κ(2)
C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_full | Dicarbonylchlorido(phenoxythiocarbonyl-κ(2)
C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_fullStr | Dicarbonylchlorido(phenoxythiocarbonyl-κ(2)
C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_full_unstemmed | Dicarbonylchlorido(phenoxythiocarbonyl-κ(2)
C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_short | Dicarbonylchlorido(phenoxythiocarbonyl-κ(2)
C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_sort | dicarbonylchlorido(phenoxythiocarbonyl-κ(2)
c,s)bis(triphenylphosphane-κp)molybdenum(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050204/ https://www.ncbi.nlm.nih.gov/pubmed/21522529 http://dx.doi.org/10.1107/S1600536810052530 |
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