The azide-bridged mixed-valent cobalt(II,III) compound [(CH(3))(3)NH](2)[Co(II)Co(2) (III)(N(3))(10)]

The crystal structure of the title compound, poly[bis­(tri­methyl­ammonium) hexa-μ(1,1)-azido-tetra­azido­tricobalt­ate(II,III)], [(CH(3))(3)NH](2)[Co(II)Co(III) (2)(N(3))(10)], consists of anionic chains [Co(II)Co(III) (2)(N(3))(10)](2−) extending parallel to the c axis and [(CH(3))(3)NH](+) counte...

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Detalles Bibliográficos
Autores principales: Liu, Yan-Ju, Li, Yu-Xian, Xu, Min, Wang, Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050209/
https://www.ncbi.nlm.nih.gov/pubmed/21522551
http://dx.doi.org/10.1107/S1600536810049421
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author Liu, Yan-Ju
Li, Yu-Xian
Xu, Min
Wang, Xia
author_facet Liu, Yan-Ju
Li, Yu-Xian
Xu, Min
Wang, Xia
author_sort Liu, Yan-Ju
collection PubMed
description The crystal structure of the title compound, poly[bis­(tri­methyl­ammonium) hexa-μ(1,1)-azido-tetra­azido­tricobalt­ate(II,III)], [(CH(3))(3)NH](2)[Co(II)Co(III) (2)(N(3))(10)], consists of anionic chains [Co(II)Co(III) (2)(N(3))(10)](2−) extending parallel to the c axis and [(CH(3))(3)NH](+) counter-cations situated between the chains. In the anionic chain, one tetra­hedrally coordinated Co(II) atom (site symmetry 2) and two octa­hedrally coordinated Co(III) atoms are arranged alternately and are linked by μ(1,1)-azide bridges. The anionic chains and cations are connected via N—H⋯N hydrogen bonding into a three-dimensional structure.
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spelling pubmed-30502092011-04-26 The azide-bridged mixed-valent cobalt(II,III) compound [(CH(3))(3)NH](2)[Co(II)Co(2) (III)(N(3))(10)] Liu, Yan-Ju Li, Yu-Xian Xu, Min Wang, Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, poly[bis­(tri­methyl­ammonium) hexa-μ(1,1)-azido-tetra­azido­tricobalt­ate(II,III)], [(CH(3))(3)NH](2)[Co(II)Co(III) (2)(N(3))(10)], consists of anionic chains [Co(II)Co(III) (2)(N(3))(10)](2−) extending parallel to the c axis and [(CH(3))(3)NH](+) counter-cations situated between the chains. In the anionic chain, one tetra­hedrally coordinated Co(II) atom (site symmetry 2) and two octa­hedrally coordinated Co(III) atoms are arranged alternately and are linked by μ(1,1)-azide bridges. The anionic chains and cations are connected via N—H⋯N hydrogen bonding into a three-dimensional structure. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050209/ /pubmed/21522551 http://dx.doi.org/10.1107/S1600536810049421 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yan-Ju
Li, Yu-Xian
Xu, Min
Wang, Xia
The azide-bridged mixed-valent cobalt(II,III) compound [(CH(3))(3)NH](2)[Co(II)Co(2) (III)(N(3))(10)]
title The azide-bridged mixed-valent cobalt(II,III) compound [(CH(3))(3)NH](2)[Co(II)Co(2) (III)(N(3))(10)]
title_full The azide-bridged mixed-valent cobalt(II,III) compound [(CH(3))(3)NH](2)[Co(II)Co(2) (III)(N(3))(10)]
title_fullStr The azide-bridged mixed-valent cobalt(II,III) compound [(CH(3))(3)NH](2)[Co(II)Co(2) (III)(N(3))(10)]
title_full_unstemmed The azide-bridged mixed-valent cobalt(II,III) compound [(CH(3))(3)NH](2)[Co(II)Co(2) (III)(N(3))(10)]
title_short The azide-bridged mixed-valent cobalt(II,III) compound [(CH(3))(3)NH](2)[Co(II)Co(2) (III)(N(3))(10)]
title_sort azide-bridged mixed-valent cobalt(ii,iii) compound [(ch(3))(3)nh](2)[co(ii)co(2) (iii)(n(3))(10)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050209/
https://www.ncbi.nlm.nih.gov/pubmed/21522551
http://dx.doi.org/10.1107/S1600536810049421
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