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Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)]
In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone molecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creatin...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050211/ https://www.ncbi.nlm.nih.gov/pubmed/21522523 http://dx.doi.org/10.1107/S160053681004986X |
Sumario: | In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone molecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creating five- and six-membered chelate metallarings. The pyridine molecule completes the square-planar base of the copper coordination environment. The crystal structure displays zigzag polymeric Cu—O—Cu chains along [001]. Several weak π–π interactions between benzothiazole rings were found in the same direction [centroid–centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å]. |
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