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Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothia­zol-2-ylsulfan­yl)-N′-(2-oxidobenzyl­idene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)]

In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone mol­ecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creatin...

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Detalles Bibliográficos
Autores principales: Bon, Vladimir V., Orysyk, Svitlana I., Pekhnyo, Vasily I.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050211/
https://www.ncbi.nlm.nih.gov/pubmed/21522523
http://dx.doi.org/10.1107/S160053681004986X
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author Bon, Vladimir V.
Orysyk, Svitlana I.
Pekhnyo, Vasily I.
author_facet Bon, Vladimir V.
Orysyk, Svitlana I.
Pekhnyo, Vasily I.
author_sort Bon, Vladimir V.
collection PubMed
description In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone mol­ecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creating five- and six-membered chelate metallarings. The pyridine mol­ecule completes the square-planar base of the copper coordination environment. The crystal structure displays zigzag polymeric Cu—O—Cu chains along [001]. Several weak π–π inter­actions between benzothia­zole rings were found in the same direction [centroid–centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å].
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spelling pubmed-30502112011-04-26 Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothia­zol-2-ylsulfan­yl)-N′-(2-oxidobenzyl­idene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)] Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone mol­ecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creating five- and six-membered chelate metallarings. The pyridine mol­ecule completes the square-planar base of the copper coordination environment. The crystal structure displays zigzag polymeric Cu—O—Cu chains along [001]. Several weak π–π inter­actions between benzothia­zole rings were found in the same direction [centroid–centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å]. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050211/ /pubmed/21522523 http://dx.doi.org/10.1107/S160053681004986X Text en © Bon et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bon, Vladimir V.
Orysyk, Svitlana I.
Pekhnyo, Vasily I.
Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothia­zol-2-ylsulfan­yl)-N′-(2-oxidobenzyl­idene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)]
title Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothia­zol-2-ylsulfan­yl)-N′-(2-oxidobenzyl­idene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)]
title_full Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothia­zol-2-ylsulfan­yl)-N′-(2-oxidobenzyl­idene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)]
title_fullStr Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothia­zol-2-ylsulfan­yl)-N′-(2-oxidobenzyl­idene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)]
title_full_unstemmed Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothia­zol-2-ylsulfan­yl)-N′-(2-oxidobenzyl­idene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)]
title_short Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothia­zol-2-ylsulfan­yl)-N′-(2-oxidobenzyl­idene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)]
title_sort poly[[μ(2)-(1z,n′e)-2-(1,3-benzothia­zol-2-ylsulfan­yl)-n′-(2-oxidobenzyl­idene-κ(2) o:o)acetohydrazidato-κ(2) o,n′](pyridine-κn)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050211/
https://www.ncbi.nlm.nih.gov/pubmed/21522523
http://dx.doi.org/10.1107/S160053681004986X
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