Cargando…
Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)]
In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone molecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creatin...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050211/ https://www.ncbi.nlm.nih.gov/pubmed/21522523 http://dx.doi.org/10.1107/S160053681004986X |
_version_ | 1782199310692122624 |
---|---|
author | Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. |
author_facet | Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. |
author_sort | Bon, Vladimir V. |
collection | PubMed |
description | In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone molecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creating five- and six-membered chelate metallarings. The pyridine molecule completes the square-planar base of the copper coordination environment. The crystal structure displays zigzag polymeric Cu—O—Cu chains along [001]. Several weak π–π interactions between benzothiazole rings were found in the same direction [centroid–centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å]. |
format | Text |
id | pubmed-3050211 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30502112011-04-26 Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)] Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone molecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creating five- and six-membered chelate metallarings. The pyridine molecule completes the square-planar base of the copper coordination environment. The crystal structure displays zigzag polymeric Cu—O—Cu chains along [001]. Several weak π–π interactions between benzothiazole rings were found in the same direction [centroid–centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å]. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050211/ /pubmed/21522523 http://dx.doi.org/10.1107/S160053681004986X Text en © Bon et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ(2) O:O)acetohydrazidato-κ(2) O,N′](pyridine-κN)copper(II)] |
title | Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ(2)
O:O)acetohydrazidato-κ(2)
O,N′](pyridine-κN)copper(II)] |
title_full | Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ(2)
O:O)acetohydrazidato-κ(2)
O,N′](pyridine-κN)copper(II)] |
title_fullStr | Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ(2)
O:O)acetohydrazidato-κ(2)
O,N′](pyridine-κN)copper(II)] |
title_full_unstemmed | Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ(2)
O:O)acetohydrazidato-κ(2)
O,N′](pyridine-κN)copper(II)] |
title_short | Poly[[μ(2)-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ(2)
O:O)acetohydrazidato-κ(2)
O,N′](pyridine-κN)copper(II)] |
title_sort | poly[[μ(2)-(1z,n′e)-2-(1,3-benzothiazol-2-ylsulfanyl)-n′-(2-oxidobenzylidene-κ(2)
o:o)acetohydrazidato-κ(2)
o,n′](pyridine-κn)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050211/ https://www.ncbi.nlm.nih.gov/pubmed/21522523 http://dx.doi.org/10.1107/S160053681004986X |
work_keys_str_mv | AT bonvladimirv polym21zne213benzothiazol2ylsulfanyln2oxidobenzylidenek2ooacetohydrazidatok2onpyridinekncopperii AT orysyksvitlanai polym21zne213benzothiazol2ylsulfanyln2oxidobenzylidenek2ooacetohydrazidatok2onpyridinekncopperii AT pekhnyovasilyi polym21zne213benzothiazol2ylsulfanyln2oxidobenzylidenek2ooacetohydrazidatok2onpyridinekncopperii |