(4-Nitro­phenolato)(subphthalo­cyaninato)boron(III)

The main feature of the structure of the title compound, C(30)H(16)BN(7)O(3) or NO(2)PhO-BsubPc, are pairs of mol­ecules linked through π-inter­actions between the concave faces of the BsubPc fragments at a distance of 3.5430 (11) Å across an inversion centre. However, the angle between the planes o...

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Detalles Bibliográficos
Autores principales: Paton, Andrew S., Lough, Alan J., Bender, Timothy P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050212/
https://www.ncbi.nlm.nih.gov/pubmed/21522767
http://dx.doi.org/10.1107/S1600536810050580
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author Paton, Andrew S.
Lough, Alan J.
Bender, Timothy P.
author_facet Paton, Andrew S.
Lough, Alan J.
Bender, Timothy P.
author_sort Paton, Andrew S.
collection PubMed
description The main feature of the structure of the title compound, C(30)H(16)BN(7)O(3) or NO(2)PhO-BsubPc, are pairs of mol­ecules linked through π-inter­actions between the concave faces of the BsubPc fragments at a distance of 3.5430 (11) Å across an inversion centre. However, the angle between the planes of the five- and six-menbered rings involved in this inter­action is 1.44 (10)°, causing the inter­acting BsubPcs units to be slightly askew rather than parallel as is typical for π-stacking inter­actions.
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spelling pubmed-30502122011-04-26 (4-Nitro­phenolato)(subphthalo­cyaninato)boron(III) Paton, Andrew S. Lough, Alan J. Bender, Timothy P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The main feature of the structure of the title compound, C(30)H(16)BN(7)O(3) or NO(2)PhO-BsubPc, are pairs of mol­ecules linked through π-inter­actions between the concave faces of the BsubPc fragments at a distance of 3.5430 (11) Å across an inversion centre. However, the angle between the planes of the five- and six-menbered rings involved in this inter­action is 1.44 (10)°, causing the inter­acting BsubPcs units to be slightly askew rather than parallel as is typical for π-stacking inter­actions. International Union of Crystallography 2010-12-08 /pmc/articles/PMC3050212/ /pubmed/21522767 http://dx.doi.org/10.1107/S1600536810050580 Text en © Paton et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Paton, Andrew S.
Lough, Alan J.
Bender, Timothy P.
(4-Nitro­phenolato)(subphthalo­cyaninato)boron(III)
title (4-Nitro­phenolato)(subphthalo­cyaninato)boron(III)
title_full (4-Nitro­phenolato)(subphthalo­cyaninato)boron(III)
title_fullStr (4-Nitro­phenolato)(subphthalo­cyaninato)boron(III)
title_full_unstemmed (4-Nitro­phenolato)(subphthalo­cyaninato)boron(III)
title_short (4-Nitro­phenolato)(subphthalo­cyaninato)boron(III)
title_sort (4-nitro­phenolato)(subphthalo­cyaninato)boron(iii)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050212/
https://www.ncbi.nlm.nih.gov/pubmed/21522767
http://dx.doi.org/10.1107/S1600536810050580
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AT bendertimothyp 4nitrophenolatosubphthalocyaninatoboroniii

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