Chlorido(η(4)-1,5-cyclo­octa­diene)[(penta­fluoro­eth­yl)diphenyl­phosphane]iridium(I)

The title structure,[IrCl(C(8)H(12))(C(14)H(10)F(5)P)], reveals that (C(2)F(5))PPh(2) (penta­fluoro­ethyl­diphenyl­phosphane or pfepp) disrupts the iridium dimer [(cod)IrCl](2) (cod = cyclo­octa-1,5-diene) by rupturing the bridging chloride ligands and binding in the open coordination site to form (...

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Detalles Bibliográficos
Autores principales: Choate, Michelle M., Peters, R. Gregory, Baughman, Russell G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050217/
https://www.ncbi.nlm.nih.gov/pubmed/21522590
http://dx.doi.org/10.1107/S160053681005141X
Descripción
Sumario:The title structure,[IrCl(C(8)H(12))(C(14)H(10)F(5)P)], reveals that (C(2)F(5))PPh(2) (penta­fluoro­ethyl­diphenyl­phosphane or pfepp) disrupts the iridium dimer [(cod)IrCl](2) (cod = cyclo­octa-1,5-diene) by rupturing the bridging chloride ligands and binding in the open coordination site to form (cod)Ir(pfepp)Cl with the Ir(I) atom in a distorted square-planar coordination environment. The structure deviates very little from the Ir(I)–triphenyl­phosphine analog, although a significantly (∼20σ) shorter Ir—P bond is noted for the title compound.

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