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Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I)
The title structure,[IrCl(C(8)H(12))(C(14)H(10)F(5)P)], reveals that (C(2)F(5))PPh(2) (pentafluoroethyldiphenylphosphane or pfepp) disrupts the iridium dimer [(cod)IrCl](2) (cod = cycloocta-1,5-diene) by rupturing the bridging chloride ligands and binding in the open coordination site to form (...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050217/ https://www.ncbi.nlm.nih.gov/pubmed/21522590 http://dx.doi.org/10.1107/S160053681005141X |
| _version_ | 1782199312132866048 |
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| author | Choate, Michelle M. Peters, R. Gregory Baughman, Russell G. |
| author_facet | Choate, Michelle M. Peters, R. Gregory Baughman, Russell G. |
| author_sort | Choate, Michelle M. |
| collection | PubMed |
| description | The title structure,[IrCl(C(8)H(12))(C(14)H(10)F(5)P)], reveals that (C(2)F(5))PPh(2) (pentafluoroethyldiphenylphosphane or pfepp) disrupts the iridium dimer [(cod)IrCl](2) (cod = cycloocta-1,5-diene) by rupturing the bridging chloride ligands and binding in the open coordination site to form (cod)Ir(pfepp)Cl with the Ir(I) atom in a distorted square-planar coordination environment. The structure deviates very little from the Ir(I)–triphenylphosphine analog, although a significantly (∼20σ) shorter Ir—P bond is noted for the title compound. |
| format | Text |
| id | pubmed-3050217 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30502172011-04-26 Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I) Choate, Michelle M. Peters, R. Gregory Baughman, Russell G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title structure,[IrCl(C(8)H(12))(C(14)H(10)F(5)P)], reveals that (C(2)F(5))PPh(2) (pentafluoroethyldiphenylphosphane or pfepp) disrupts the iridium dimer [(cod)IrCl](2) (cod = cycloocta-1,5-diene) by rupturing the bridging chloride ligands and binding in the open coordination site to form (cod)Ir(pfepp)Cl with the Ir(I) atom in a distorted square-planar coordination environment. The structure deviates very little from the Ir(I)–triphenylphosphine analog, although a significantly (∼20σ) shorter Ir—P bond is noted for the title compound. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050217/ /pubmed/21522590 http://dx.doi.org/10.1107/S160053681005141X Text en © Choate et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Choate, Michelle M. Peters, R. Gregory Baughman, Russell G. Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I) |
| title | Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I) |
| title_full | Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I) |
| title_fullStr | Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I) |
| title_full_unstemmed | Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I) |
| title_short | Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I) |
| title_sort | chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050217/ https://www.ncbi.nlm.nih.gov/pubmed/21522590 http://dx.doi.org/10.1107/S160053681005141X |
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