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Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I)
The title structure,[IrCl(C(8)H(12))(C(14)H(10)F(5)P)], reveals that (C(2)F(5))PPh(2) (pentafluoroethyldiphenylphosphane or pfepp) disrupts the iridium dimer [(cod)IrCl](2) (cod = cycloocta-1,5-diene) by rupturing the bridging chloride ligands and binding in the open coordination site to form (...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050217/ https://www.ncbi.nlm.nih.gov/pubmed/21522590 http://dx.doi.org/10.1107/S160053681005141X |