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Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-κ(2) N′,O}copper(II)
In the title compound, [CuCl(2)(C(9)H(11)N(3)O)], the Cu(II) atom is in a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu—Cl distance of 2.4892 (9) Å. In co...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050222/ https://www.ncbi.nlm.nih.gov/pubmed/21522534 http://dx.doi.org/10.1107/S1600536810053195 |
| _version_ | 1782199313285251072 |
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| author | Datta, Amitabha Das, Kuheli Jhou, Yan-Ming Huang, Jui-Hsien Lee, Hon Man |
| author_facet | Datta, Amitabha Das, Kuheli Jhou, Yan-Ming Huang, Jui-Hsien Lee, Hon Man |
| author_sort | Datta, Amitabha |
| collection | PubMed |
| description | In the title compound, [CuCl(2)(C(9)H(11)N(3)O)], the Cu(II) atom is in a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu—Cl distance of 2.4892 (9) Å. In contrast, the Cu—Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å]. Intermolecular N—H⋯Cl and C—H⋯Cl hydrogen bonds link the complexes into a three-dimensional network. |
| format | Text |
| id | pubmed-3050222 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30502222011-04-26 Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-κ(2) N′,O}copper(II) Datta, Amitabha Das, Kuheli Jhou, Yan-Ming Huang, Jui-Hsien Lee, Hon Man Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(2)(C(9)H(11)N(3)O)], the Cu(II) atom is in a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu—Cl distance of 2.4892 (9) Å. In contrast, the Cu—Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å]. Intermolecular N—H⋯Cl and C—H⋯Cl hydrogen bonds link the complexes into a three-dimensional network. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050222/ /pubmed/21522534 http://dx.doi.org/10.1107/S1600536810053195 Text en © Datta et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Datta, Amitabha Das, Kuheli Jhou, Yan-Ming Huang, Jui-Hsien Lee, Hon Man Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-κ(2) N′,O}copper(II) |
| title | Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_full | Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_fullStr | Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_full_unstemmed | Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_short | Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_sort | dichlorido{n′-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-κ(2)
n′,o}copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050222/ https://www.ncbi.nlm.nih.gov/pubmed/21522534 http://dx.doi.org/10.1107/S1600536810053195 |
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