1-(4-Bromo­phen­yl)-3-butano­ylthio­urea

In the title compound, C(11)H(13)BrN(2)OS, there are two independent mol­ecules (A and B) in the asymmetric unit. The dihedral angle between the mean planes of the benzene ring and the carbamothioyl group is 63.66 (mol­ecule A) and 80.3 (0)° (mol­ecule B). The butanamide group in mol­ecule A is diso...

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Detalles Bibliográficos
Autores principales: Saeed, Sohail, Rashid, Naghmana, Jasinski, Jerry P., Butcher, Ray J., Shoaib, Muhammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050228/
https://www.ncbi.nlm.nih.gov/pubmed/21522755
http://dx.doi.org/10.1107/S1600536810050373
Descripción
Sumario:In the title compound, C(11)H(13)BrN(2)OS, there are two independent mol­ecules (A and B) in the asymmetric unit. The dihedral angle between the mean planes of the benzene ring and the carbamothioyl group is 63.66 (mol­ecule A) and 80.3 (0)° (mol­ecule B). The butanamide group in mol­ecule A is disordered [0.532 (6) and 0.468 (6) occupancy]. The carbamothioyl group is twisted by 63.6 (6) (mol­ecule A) and 80.3 (0)° (mol­ecule B) from the respective benzene ring. A strong intra­molecular N—H⋯O hydrogen bond occurs in each mol­ecule. The crystal packing is stabilized by weak inter­molecular N—H⋯O and N—H⋯S hydrogen-bond inter­actions, the latter forming an infinite co-operative hydrogen-bonded two-dimensional network along [110].

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