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(E)-4-[2-(4-Eth­oxy­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate methanol hemisolvate

In the title compound, C(16)H(18)NO(+)·C(6)H(4)BrO(3)S(−)·0.5CH(3)OH, the cation exists in the E configuration and the whole mol­ecule of the cation, except for the O atom of the eth­oxy group, is disordered with a site-occupancy ratio of 0.695 (5):0.305 (5). The cation is disordered in such a way t...

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Detalles Bibliográficos
Autores principales: Fun, Hoong Kun, Chantrapromma, Suchada, Jansrisewangwong, Patcharaporn
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050231/
https://www.ncbi.nlm.nih.gov/pubmed/21522618
http://dx.doi.org/10.1107/S1600536810050944
Descripción
Sumario:In the title compound, C(16)H(18)NO(+)·C(6)H(4)BrO(3)S(−)·0.5CH(3)OH, the cation exists in the E configuration and the whole mol­ecule of the cation, except for the O atom of the eth­oxy group, is disordered with a site-occupancy ratio of 0.695 (5):0.305 (5). The cation is disordered in such a way that the ethenyl units of the major and minor components are related by 180° around the long mol­ecular axis. In the major component, the cation is almost planar, the dihedral angle between the pyridinium and benzene rings being 0.8 (3)°, whereas in the minor component, the dihedral angle between the two aromatic rings is 4.2 (6)°. In the crystal, the cations are stacked in an anti­parallel manner along the a axis, while the anions and methanol mol­ecules are linked through O—H⋯O hydrogen bonds and Br⋯O short contacts [3.0248 (13) Å] into a tape along the same direction. The three components are further linked by weak C—H⋯O, C—H⋯Br and C—H⋯π inter­actions.