N′-(2-Chloro­benzyl­idene)-2-fluoro­benzohydrazide

The title hydrazone compound, C(14)H(10)ClFN(2)O, adopts an E configuration about the C=N double bond. The dihedral angle between the two substituted benzene rings is 11.6 (2)°. The F atom is disordered over two sites with occupancies of 0.488 (2) and 0.512 (2). In the crystal, mol­ecules are linked...

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Detalles Bibliográficos
Autor principal: Zhang, Wei-Guang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050234/
https://www.ncbi.nlm.nih.gov/pubmed/21522733
http://dx.doi.org/10.1107/S1600536810053043
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author Zhang, Wei-Guang
author_facet Zhang, Wei-Guang
author_sort Zhang, Wei-Guang
collection PubMed
description The title hydrazone compound, C(14)H(10)ClFN(2)O, adopts an E configuration about the C=N double bond. The dihedral angle between the two substituted benzene rings is 11.6 (2)°. The F atom is disordered over two sites with occupancies of 0.488 (2) and 0.512 (2). In the crystal, mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming chains along the a axis. C—H⋯F and C—H⋯O inter­actions also occur.
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spelling pubmed-30502342011-04-26 N′-(2-Chloro­benzyl­idene)-2-fluoro­benzohydrazide Zhang, Wei-Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title hydrazone compound, C(14)H(10)ClFN(2)O, adopts an E configuration about the C=N double bond. The dihedral angle between the two substituted benzene rings is 11.6 (2)°. The F atom is disordered over two sites with occupancies of 0.488 (2) and 0.512 (2). In the crystal, mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming chains along the a axis. C—H⋯F and C—H⋯O inter­actions also occur. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050234/ /pubmed/21522733 http://dx.doi.org/10.1107/S1600536810053043 Text en © Wei-Guang Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Wei-Guang
N′-(2-Chloro­benzyl­idene)-2-fluoro­benzohydrazide
title N′-(2-Chloro­benzyl­idene)-2-fluoro­benzohydrazide
title_full N′-(2-Chloro­benzyl­idene)-2-fluoro­benzohydrazide
title_fullStr N′-(2-Chloro­benzyl­idene)-2-fluoro­benzohydrazide
title_full_unstemmed N′-(2-Chloro­benzyl­idene)-2-fluoro­benzohydrazide
title_short N′-(2-Chloro­benzyl­idene)-2-fluoro­benzohydrazide
title_sort n′-(2-chloro­benzyl­idene)-2-fluoro­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050234/
https://www.ncbi.nlm.nih.gov/pubmed/21522733
http://dx.doi.org/10.1107/S1600536810053043
work_keys_str_mv AT zhangweiguang n2chlorobenzylidene2fluorobenzohydrazide

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