Di-μ-chlorido-bis­{[2-(benzyl­imino­meth­yl)pyridine-κ(2) N,N′]chloridomercury(II)} dichloridomercury(II)

The Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(13)H(12)N(2))(2)]·[HgCl(2)], adopts a distorted square-pyramidal geometry, being coordinated by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds [2.842...

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Autores principales: Kim, Young-Inn, Song, Young-Kwang, Yun, Seong-Jae, Kim, In-Chan, Kang, Sung Kwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050237/
https://www.ncbi.nlm.nih.gov/pubmed/21522571
http://dx.doi.org/10.1107/S1600536810050725
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author Kim, Young-Inn
Song, Young-Kwang
Yun, Seong-Jae
Kim, In-Chan
Kang, Sung Kwon
author_facet Kim, Young-Inn
Song, Young-Kwang
Yun, Seong-Jae
Kim, In-Chan
Kang, Sung Kwon
author_sort Kim, Young-Inn
collection PubMed
description The Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(13)H(12)N(2))(2)]·[HgCl(2)], adopts a distorted square-pyramidal geometry, being coordinated by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds [2.8428 (11) Å] is significantly longer than the other [2.5327 (10) Å]. In the crystal, there are weak π–π inter­actions [centroid–centroid distance = 3.630 (3) Å] between the aromatic rings of the discrete units. The HgCl(2) adduct molecule is located on an inversion centre and has an Hg—Cl bond length of 2.2875 (11) Å.
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spelling pubmed-30502372011-04-26 Di-μ-chlorido-bis­{[2-(benzyl­imino­meth­yl)pyridine-κ(2) N,N′]chloridomercury(II)} dichloridomercury(II) Kim, Young-Inn Song, Young-Kwang Yun, Seong-Jae Kim, In-Chan Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(13)H(12)N(2))(2)]·[HgCl(2)], adopts a distorted square-pyramidal geometry, being coordinated by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds [2.8428 (11) Å] is significantly longer than the other [2.5327 (10) Å]. In the crystal, there are weak π–π inter­actions [centroid–centroid distance = 3.630 (3) Å] between the aromatic rings of the discrete units. The HgCl(2) adduct molecule is located on an inversion centre and has an Hg—Cl bond length of 2.2875 (11) Å. International Union of Crystallography 2010-12-08 /pmc/articles/PMC3050237/ /pubmed/21522571 http://dx.doi.org/10.1107/S1600536810050725 Text en © Kim et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Young-Inn
Song, Young-Kwang
Yun, Seong-Jae
Kim, In-Chan
Kang, Sung Kwon
Di-μ-chlorido-bis­{[2-(benzyl­imino­meth­yl)pyridine-κ(2) N,N′]chloridomercury(II)} dichloridomercury(II)
title Di-μ-chlorido-bis­{[2-(benzyl­imino­meth­yl)pyridine-κ(2) N,N′]chloridomercury(II)} dichloridomercury(II)
title_full Di-μ-chlorido-bis­{[2-(benzyl­imino­meth­yl)pyridine-κ(2) N,N′]chloridomercury(II)} dichloridomercury(II)
title_fullStr Di-μ-chlorido-bis­{[2-(benzyl­imino­meth­yl)pyridine-κ(2) N,N′]chloridomercury(II)} dichloridomercury(II)
title_full_unstemmed Di-μ-chlorido-bis­{[2-(benzyl­imino­meth­yl)pyridine-κ(2) N,N′]chloridomercury(II)} dichloridomercury(II)
title_short Di-μ-chlorido-bis­{[2-(benzyl­imino­meth­yl)pyridine-κ(2) N,N′]chloridomercury(II)} dichloridomercury(II)
title_sort di-μ-chlorido-bis­{[2-(benzyl­imino­meth­yl)pyridine-κ(2) n,n′]chloridomercury(ii)} dichloridomercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050237/
https://www.ncbi.nlm.nih.gov/pubmed/21522571
http://dx.doi.org/10.1107/S1600536810050725
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