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Bis(2-{2-[2-(benzyl­carbamo­yl)phen­oxy]acetamido}­eth­yl)ammonium nitrate ethanol disolvate

In the title compound, C(36)H(40)N(5)O(6) (+)·NO(3) (−)·2C(2)H(5)OH, the nitrate anion is disordered over the two orientations of equal occupancy while the solvent mol­ecule reveals large displacement parameters. The cation is formed by protonation of the N atom of a secondary amine in the middle of...

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Detalles Bibliográficos
Autores principales: Liu, Jiaji, Tang, Xiaoliang, Lu, Zhengdan, Zhang, Guolin, Liu, Weisheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050242/
https://www.ncbi.nlm.nih.gov/pubmed/21522705
http://dx.doi.org/10.1107/S1600536810052670
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author Liu, Jiaji
Tang, Xiaoliang
Lu, Zhengdan
Zhang, Guolin
Liu, Weisheng
author_facet Liu, Jiaji
Tang, Xiaoliang
Lu, Zhengdan
Zhang, Guolin
Liu, Weisheng
author_sort Liu, Jiaji
collection PubMed
description In the title compound, C(36)H(40)N(5)O(6) (+)·NO(3) (−)·2C(2)H(5)OH, the nitrate anion is disordered over the two orientations of equal occupancy while the solvent mol­ecule reveals large displacement parameters. The cation is formed by protonation of the N atom of a secondary amine in the middle of the flexible chain and the whole compound has crystallographically imposed C-2 symmetry with the crystallographic b axis. An O atom of the nitrate anion links the acidic H atoms of the cation via N—H⋯O hydrogen bonding. In addition, neighbouring cations are connected by inter­molecular N—H⋯O hydrogen bonds and π–π inter­actions between the benzamide groups of the cations [centroid–centroid distance = 4.000 (3) Å], forming a chain along [001]. The ethanol solvent mol­ecules are arranged on the side of the chain through O—H⋯O hydrogen bonds.
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spelling pubmed-30502422011-04-26 Bis(2-{2-[2-(benzyl­carbamo­yl)phen­oxy]acetamido}­eth­yl)ammonium nitrate ethanol disolvate Liu, Jiaji Tang, Xiaoliang Lu, Zhengdan Zhang, Guolin Liu, Weisheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(36)H(40)N(5)O(6) (+)·NO(3) (−)·2C(2)H(5)OH, the nitrate anion is disordered over the two orientations of equal occupancy while the solvent mol­ecule reveals large displacement parameters. The cation is formed by protonation of the N atom of a secondary amine in the middle of the flexible chain and the whole compound has crystallographically imposed C-2 symmetry with the crystallographic b axis. An O atom of the nitrate anion links the acidic H atoms of the cation via N—H⋯O hydrogen bonding. In addition, neighbouring cations are connected by inter­molecular N—H⋯O hydrogen bonds and π–π inter­actions between the benzamide groups of the cations [centroid–centroid distance = 4.000 (3) Å], forming a chain along [001]. The ethanol solvent mol­ecules are arranged on the side of the chain through O—H⋯O hydrogen bonds. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050242/ /pubmed/21522705 http://dx.doi.org/10.1107/S1600536810052670 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Jiaji
Tang, Xiaoliang
Lu, Zhengdan
Zhang, Guolin
Liu, Weisheng
Bis(2-{2-[2-(benzyl­carbamo­yl)phen­oxy]acetamido}­eth­yl)ammonium nitrate ethanol disolvate
title Bis(2-{2-[2-(benzyl­carbamo­yl)phen­oxy]acetamido}­eth­yl)ammonium nitrate ethanol disolvate
title_full Bis(2-{2-[2-(benzyl­carbamo­yl)phen­oxy]acetamido}­eth­yl)ammonium nitrate ethanol disolvate
title_fullStr Bis(2-{2-[2-(benzyl­carbamo­yl)phen­oxy]acetamido}­eth­yl)ammonium nitrate ethanol disolvate
title_full_unstemmed Bis(2-{2-[2-(benzyl­carbamo­yl)phen­oxy]acetamido}­eth­yl)ammonium nitrate ethanol disolvate
title_short Bis(2-{2-[2-(benzyl­carbamo­yl)phen­oxy]acetamido}­eth­yl)ammonium nitrate ethanol disolvate
title_sort bis(2-{2-[2-(benzyl­carbamo­yl)phen­oxy]acetamido}­eth­yl)ammonium nitrate ethanol disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050242/
https://www.ncbi.nlm.nih.gov/pubmed/21522705
http://dx.doi.org/10.1107/S1600536810052670
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