Bromidotricarbon­yl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN (3)]rhenium(I) dichloro­methane monosolvate

In the title compound, [ReBr(C(14)H(11)N(3)O)(CO)(3)]·CH(2)Cl(2), the coordination geometry of the Re(I) atom is a distorted ReC(3)N(2)Br octa­hedron with the carbonyl C atoms in a fac arrangement. Within the 2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole ligand, the dihedral angles between the oxadiaz...

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Autores principales: Shi, Lin-Fang, Li, Yan-wei, Si, Zhen-jun, Guan, Ying, Cao, Hua-ru
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050244/
https://www.ncbi.nlm.nih.gov/pubmed/21522604
http://dx.doi.org/10.1107/S160053681004969X
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author Shi, Lin-Fang
Li, Yan-wei
Si, Zhen-jun
Guan, Ying
Cao, Hua-ru
author_facet Shi, Lin-Fang
Li, Yan-wei
Si, Zhen-jun
Guan, Ying
Cao, Hua-ru
author_sort Shi, Lin-Fang
collection PubMed
description In the title compound, [ReBr(C(14)H(11)N(3)O)(CO)(3)]·CH(2)Cl(2), the coordination geometry of the Re(I) atom is a distorted ReC(3)N(2)Br octa­hedron with the carbonyl C atoms in a fac arrangement. Within the 2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole ligand, the dihedral angles between the oxadiazole ring and the pyridine (py) and benzene (bz) rings are 1.7 (2) and 7.1 (2)°, respectively, and the dihedral angle between the py and bz rings is 5.5 (2)°. In the crystal, aromatic π–π stacking between the oxadiazole rings of adjacent mol­ecules [centroid–centroid separation = 3.465 (3) Å] is seen.
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spelling pubmed-30502442011-04-26 Bromidotricarbon­yl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN (3)]rhenium(I) dichloro­methane monosolvate Shi, Lin-Fang Li, Yan-wei Si, Zhen-jun Guan, Ying Cao, Hua-ru Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ReBr(C(14)H(11)N(3)O)(CO)(3)]·CH(2)Cl(2), the coordination geometry of the Re(I) atom is a distorted ReC(3)N(2)Br octa­hedron with the carbonyl C atoms in a fac arrangement. Within the 2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole ligand, the dihedral angles between the oxadiazole ring and the pyridine (py) and benzene (bz) rings are 1.7 (2) and 7.1 (2)°, respectively, and the dihedral angle between the py and bz rings is 5.5 (2)°. In the crystal, aromatic π–π stacking between the oxadiazole rings of adjacent mol­ecules [centroid–centroid separation = 3.465 (3) Å] is seen. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050244/ /pubmed/21522604 http://dx.doi.org/10.1107/S160053681004969X Text en © Shi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Lin-Fang
Li, Yan-wei
Si, Zhen-jun
Guan, Ying
Cao, Hua-ru
Bromidotricarbon­yl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN (3)]rhenium(I) dichloro­methane monosolvate
title Bromidotricarbon­yl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN (3)]rhenium(I) dichloro­methane monosolvate
title_full Bromidotricarbon­yl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN (3)]rhenium(I) dichloro­methane monosolvate
title_fullStr Bromidotricarbon­yl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN (3)]rhenium(I) dichloro­methane monosolvate
title_full_unstemmed Bromidotricarbon­yl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN (3)]rhenium(I) dichloro­methane monosolvate
title_short Bromidotricarbon­yl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN (3)]rhenium(I) dichloro­methane monosolvate
title_sort bromidotricarbon­yl[2-(pyridin-2-yl-κn)-5-p-tolyl-1,3,4-oxadiazole-κn (3)]rhenium(i) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050244/
https://www.ncbi.nlm.nih.gov/pubmed/21522604
http://dx.doi.org/10.1107/S160053681004969X
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AT guanying bromidotricarbonyl2pyridin2ylkn5ptolyl134oxadiazolekn3rheniumidichloromethanemonosolvate
AT caohuaru bromidotricarbonyl2pyridin2ylkn5ptolyl134oxadiazolekn3rheniumidichloromethanemonosolvate

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