2-Chloro-N′-[4-(dimethyl­amino)­benzyl­idene]-N-[4-(3-methyl-3-phenyl­cyclo­but­yl)-1,3-thia­zol-2-yl]acetohydrazide

The mol­ecular conformation of the title compound, C(25)H(27)ClN(4)OS, is stabilized by an intra­molecular benzyl­idine C—H⋯N(thia­zole) hydrogen bond. The thiazole ring makes dihedral angles of 12.0 (3) and 20.4 (2)°, respectively, with the phenyl and benzene rings, while the phenyl and benzene rin...

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Autores principales: Inkaya, Ersin, Dinçer, Muharrem, Çukurovalı, Alaaddin, Yılmaz, Engin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050246/
https://www.ncbi.nlm.nih.gov/pubmed/21522642
http://dx.doi.org/10.1107/S1600536810049962
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author Inkaya, Ersin
Dinçer, Muharrem
Çukurovalı, Alaaddin
Yılmaz, Engin
author_facet Inkaya, Ersin
Dinçer, Muharrem
Çukurovalı, Alaaddin
Yılmaz, Engin
author_sort Inkaya, Ersin
collection PubMed
description The mol­ecular conformation of the title compound, C(25)H(27)ClN(4)OS, is stabilized by an intra­molecular benzyl­idine C—H⋯N(thia­zole) hydrogen bond. The thiazole ring makes dihedral angles of 12.0 (3) and 20.4 (2)°, respectively, with the phenyl and benzene rings, while the phenyl and benzene rings make a dihedral angle of 22.6 (2)°. The crystal packing involves weak inter­molecular thia­zole C—H⋯O(carbon­yl) and methyl C—H⋯π hydrogen-bonding associations.
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spelling pubmed-30502462011-04-26 2-Chloro-N′-[4-(dimethyl­amino)­benzyl­idene]-N-[4-(3-methyl-3-phenyl­cyclo­but­yl)-1,3-thia­zol-2-yl]acetohydrazide Inkaya, Ersin Dinçer, Muharrem Çukurovalı, Alaaddin Yılmaz, Engin Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular conformation of the title compound, C(25)H(27)ClN(4)OS, is stabilized by an intra­molecular benzyl­idine C—H⋯N(thia­zole) hydrogen bond. The thiazole ring makes dihedral angles of 12.0 (3) and 20.4 (2)°, respectively, with the phenyl and benzene rings, while the phenyl and benzene rings make a dihedral angle of 22.6 (2)°. The crystal packing involves weak inter­molecular thia­zole C—H⋯O(carbon­yl) and methyl C—H⋯π hydrogen-bonding associations. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050246/ /pubmed/21522642 http://dx.doi.org/10.1107/S1600536810049962 Text en © Ínkaya et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Inkaya, Ersin
Dinçer, Muharrem
Çukurovalı, Alaaddin
Yılmaz, Engin
2-Chloro-N′-[4-(dimethyl­amino)­benzyl­idene]-N-[4-(3-methyl-3-phenyl­cyclo­but­yl)-1,3-thia­zol-2-yl]acetohydrazide
title 2-Chloro-N′-[4-(dimethyl­amino)­benzyl­idene]-N-[4-(3-methyl-3-phenyl­cyclo­but­yl)-1,3-thia­zol-2-yl]acetohydrazide
title_full 2-Chloro-N′-[4-(dimethyl­amino)­benzyl­idene]-N-[4-(3-methyl-3-phenyl­cyclo­but­yl)-1,3-thia­zol-2-yl]acetohydrazide
title_fullStr 2-Chloro-N′-[4-(dimethyl­amino)­benzyl­idene]-N-[4-(3-methyl-3-phenyl­cyclo­but­yl)-1,3-thia­zol-2-yl]acetohydrazide
title_full_unstemmed 2-Chloro-N′-[4-(dimethyl­amino)­benzyl­idene]-N-[4-(3-methyl-3-phenyl­cyclo­but­yl)-1,3-thia­zol-2-yl]acetohydrazide
title_short 2-Chloro-N′-[4-(dimethyl­amino)­benzyl­idene]-N-[4-(3-methyl-3-phenyl­cyclo­but­yl)-1,3-thia­zol-2-yl]acetohydrazide
title_sort 2-chloro-n′-[4-(dimethyl­amino)­benzyl­idene]-n-[4-(3-methyl-3-phenyl­cyclo­but­yl)-1,3-thia­zol-2-yl]acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050246/
https://www.ncbi.nlm.nih.gov/pubmed/21522642
http://dx.doi.org/10.1107/S1600536810049962
work_keys_str_mv AT inkayaersin 2chloron4dimethylaminobenzylidenen43methyl3phenylcyclobutyl13thiazol2ylacetohydrazide
AT dincermuharrem 2chloron4dimethylaminobenzylidenen43methyl3phenylcyclobutyl13thiazol2ylacetohydrazide
AT cukurovalıalaaddin 2chloron4dimethylaminobenzylidenen43methyl3phenylcyclobutyl13thiazol2ylacetohydrazide
AT yılmazengin 2chloron4dimethylaminobenzylidenen43methyl3phenylcyclobutyl13thiazol2ylacetohydrazide

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