rac-Diethyl 6-hy­droxy-4-[(2-hy­droxy­eth­yl)amino]-6-methyl-2-phenyl­cyclo­hex-3-ene-1,3-dicarboxyl­ate

The title compound, C(21)H(29)NO(6), is chiral with three stereogenic centres. The crystal is a racemate and consists of enanti­omeric pairs with the relative configuration rac-(2R*,3S*,4R*). The ethyl fragment of the eth­oxy­carbonyl group at position 1 is disordered in a 0.60:0.40 ratio. The cryst...

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Detalles Bibliográficos
Autores principales: Maharramov, Abel M., Ismiyev, Arif I., Rashidov, Bahruz A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050247/
https://www.ncbi.nlm.nih.gov/pubmed/21522691
http://dx.doi.org/10.1107/S1600536810052669
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author Maharramov, Abel M.
Ismiyev, Arif I.
Rashidov, Bahruz A.
author_facet Maharramov, Abel M.
Ismiyev, Arif I.
Rashidov, Bahruz A.
author_sort Maharramov, Abel M.
collection PubMed
description The title compound, C(21)H(29)NO(6), is chiral with three stereogenic centres. The crystal is a racemate and consists of enanti­omeric pairs with the relative configuration rac-(2R*,3S*,4R*). The ethyl fragment of the eth­oxy­carbonyl group at position 1 is disordered in a 0.60:0.40 ratio. The crystal packing displays inter­molecular O—H⋯O hydrogen bonding. An intra­molecular N—H⋯O hydrogen bond also occurs.
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spelling pubmed-30502472011-04-26 rac-Diethyl 6-hy­droxy-4-[(2-hy­droxy­eth­yl)amino]-6-methyl-2-phenyl­cyclo­hex-3-ene-1,3-dicarboxyl­ate Maharramov, Abel M. Ismiyev, Arif I. Rashidov, Bahruz A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(29)NO(6), is chiral with three stereogenic centres. The crystal is a racemate and consists of enanti­omeric pairs with the relative configuration rac-(2R*,3S*,4R*). The ethyl fragment of the eth­oxy­carbonyl group at position 1 is disordered in a 0.60:0.40 ratio. The crystal packing displays inter­molecular O—H⋯O hydrogen bonding. An intra­molecular N—H⋯O hydrogen bond also occurs. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050247/ /pubmed/21522691 http://dx.doi.org/10.1107/S1600536810052669 Text en © Maharramov et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Maharramov, Abel M.
Ismiyev, Arif I.
Rashidov, Bahruz A.
rac-Diethyl 6-hy­droxy-4-[(2-hy­droxy­eth­yl)amino]-6-methyl-2-phenyl­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title rac-Diethyl 6-hy­droxy-4-[(2-hy­droxy­eth­yl)amino]-6-methyl-2-phenyl­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_full rac-Diethyl 6-hy­droxy-4-[(2-hy­droxy­eth­yl)amino]-6-methyl-2-phenyl­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_fullStr rac-Diethyl 6-hy­droxy-4-[(2-hy­droxy­eth­yl)amino]-6-methyl-2-phenyl­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_full_unstemmed rac-Diethyl 6-hy­droxy-4-[(2-hy­droxy­eth­yl)amino]-6-methyl-2-phenyl­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_short rac-Diethyl 6-hy­droxy-4-[(2-hy­droxy­eth­yl)amino]-6-methyl-2-phenyl­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_sort rac-diethyl 6-hy­droxy-4-[(2-hy­droxy­eth­yl)amino]-6-methyl-2-phenyl­cyclo­hex-3-ene-1,3-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050247/
https://www.ncbi.nlm.nih.gov/pubmed/21522691
http://dx.doi.org/10.1107/S1600536810052669
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AT rashidovbahruza racdiethyl6hydroxy42hydroxyethylamino6methyl2phenylcyclohex3ene13dicarboxylate

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