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(4-Chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone

In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The tor...

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Detalles Bibliográficos
Autores principales: Nishijima, Takahiro, Nagasawa, Atsushi, Takada, Teruhisa, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050249/
https://www.ncbi.nlm.nih.gov/pubmed/21522662
http://dx.doi.org/10.1107/S1600536810051998
Descripción
Sumario:In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The torsion angle of the carbonyl group and naphthalene ring is 54.68 (19)° (C—C—C—O), and that of nitro group and naphthalene ring is 54.26 (18)° (O—N—C—C). In the crystal, π–π inter­actions between naphthalene systems [centroid–centroid distances = 3.5633 (9), 3,5634 (9), and 3.9758(9) Å], C—H⋯O hydrogen bonds, inter­molecular N—O⋯Cl inter­actions [2.9937 (12) Å] and C—H⋯π contacts are observed.