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(4-Chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone

In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The tor...

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Autores principales: Nishijima, Takahiro, Nagasawa, Atsushi, Takada, Teruhisa, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050249/
https://www.ncbi.nlm.nih.gov/pubmed/21522662
http://dx.doi.org/10.1107/S1600536810051998
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author Nishijima, Takahiro
Nagasawa, Atsushi
Takada, Teruhisa
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Nishijima, Takahiro
Nagasawa, Atsushi
Takada, Teruhisa
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Nishijima, Takahiro
collection PubMed
description In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The torsion angle of the carbonyl group and naphthalene ring is 54.68 (19)° (C—C—C—O), and that of nitro group and naphthalene ring is 54.26 (18)° (O—N—C—C). In the crystal, π–π inter­actions between naphthalene systems [centroid–centroid distances = 3.5633 (9), 3,5634 (9), and 3.9758(9) Å], C—H⋯O hydrogen bonds, inter­molecular N—O⋯Cl inter­actions [2.9937 (12) Å] and C—H⋯π contacts are observed.
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spelling pubmed-30502492011-04-26 (4-Chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone Nishijima, Takahiro Nagasawa, Atsushi Takada, Teruhisa Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The torsion angle of the carbonyl group and naphthalene ring is 54.68 (19)° (C—C—C—O), and that of nitro group and naphthalene ring is 54.26 (18)° (O—N—C—C). In the crystal, π–π inter­actions between naphthalene systems [centroid–centroid distances = 3.5633 (9), 3,5634 (9), and 3.9758(9) Å], C—H⋯O hydrogen bonds, inter­molecular N—O⋯Cl inter­actions [2.9937 (12) Å] and C—H⋯π contacts are observed. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050249/ /pubmed/21522662 http://dx.doi.org/10.1107/S1600536810051998 Text en © Nishijima et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nishijima, Takahiro
Nagasawa, Atsushi
Takada, Teruhisa
Okamoto, Akiko
Yonezawa, Noriyuki
(4-Chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone
title (4-Chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone
title_full (4-Chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone
title_fullStr (4-Chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone
title_full_unstemmed (4-Chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone
title_short (4-Chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone
title_sort (4-chloro­phen­yl)(2,7-dimeth­oxy-8-nitro­naphthalen-1-yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050249/
https://www.ncbi.nlm.nih.gov/pubmed/21522662
http://dx.doi.org/10.1107/S1600536810051998
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