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(4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone
In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The tor...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050249/ https://www.ncbi.nlm.nih.gov/pubmed/21522662 http://dx.doi.org/10.1107/S1600536810051998 |
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author | Nishijima, Takahiro Nagasawa, Atsushi Takada, Teruhisa Okamoto, Akiko Yonezawa, Noriyuki |
author_facet | Nishijima, Takahiro Nagasawa, Atsushi Takada, Teruhisa Okamoto, Akiko Yonezawa, Noriyuki |
author_sort | Nishijima, Takahiro |
collection | PubMed |
description | In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The torsion angle of the carbonyl group and naphthalene ring is 54.68 (19)° (C—C—C—O), and that of nitro group and naphthalene ring is 54.26 (18)° (O—N—C—C). In the crystal, π–π interactions between naphthalene systems [centroid–centroid distances = 3.5633 (9), 3,5634 (9), and 3.9758(9) Å], C—H⋯O hydrogen bonds, intermolecular N—O⋯Cl interactions [2.9937 (12) Å] and C—H⋯π contacts are observed. |
format | Text |
id | pubmed-3050249 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30502492011-04-26 (4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone Nishijima, Takahiro Nagasawa, Atsushi Takada, Teruhisa Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The torsion angle of the carbonyl group and naphthalene ring is 54.68 (19)° (C—C—C—O), and that of nitro group and naphthalene ring is 54.26 (18)° (O—N—C—C). In the crystal, π–π interactions between naphthalene systems [centroid–centroid distances = 3.5633 (9), 3,5634 (9), and 3.9758(9) Å], C—H⋯O hydrogen bonds, intermolecular N—O⋯Cl interactions [2.9937 (12) Å] and C—H⋯π contacts are observed. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050249/ /pubmed/21522662 http://dx.doi.org/10.1107/S1600536810051998 Text en © Nishijima et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Nishijima, Takahiro Nagasawa, Atsushi Takada, Teruhisa Okamoto, Akiko Yonezawa, Noriyuki (4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone |
title | (4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone |
title_full | (4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone |
title_fullStr | (4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone |
title_full_unstemmed | (4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone |
title_short | (4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone |
title_sort | (4-chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050249/ https://www.ncbi.nlm.nih.gov/pubmed/21522662 http://dx.doi.org/10.1107/S1600536810051998 |
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