2-Amino-4-methyl­pyridinium 6-carb­oxy­pyridine-2-carboxyl­ate methanol monosolvate

In the title solvated molecular salt, C(6)H(9)N(2) (+)·C(7)H(4)NO(4) (−)·CH(4)O, the pyridine N atom of 2-amino-4-methyl­pyridine is protonated and one carboxyl group of pyridine-2,6-dicarb­oxy­lic acid is deprotonated. The dihedral angles between the –CO(2) and –COH groups and the pyridine ring are...

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Autores principales: Aghabozorg, Hossein, Mofidi Rouchi, Azadeh, Mirzaei, Masoud, Notash, Behrouz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050251/
https://www.ncbi.nlm.nih.gov/pubmed/21522764
http://dx.doi.org/10.1107/S1600536810050245
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author Aghabozorg, Hossein
Mofidi Rouchi, Azadeh
Mirzaei, Masoud
Notash, Behrouz
author_facet Aghabozorg, Hossein
Mofidi Rouchi, Azadeh
Mirzaei, Masoud
Notash, Behrouz
author_sort Aghabozorg, Hossein
collection PubMed
description In the title solvated molecular salt, C(6)H(9)N(2) (+)·C(7)H(4)NO(4) (−)·CH(4)O, the pyridine N atom of 2-amino-4-methyl­pyridine is protonated and one carboxyl group of pyridine-2,6-dicarb­oxy­lic acid is deprotonated. The dihedral angles between the –CO(2) and –COH groups and the pyridine ring are 0.65 (13) and 7.4°. The crystal packing is stabilized by inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds.
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spelling pubmed-30502512011-04-26 2-Amino-4-methyl­pyridinium 6-carb­oxy­pyridine-2-carboxyl­ate methanol monosolvate Aghabozorg, Hossein Mofidi Rouchi, Azadeh Mirzaei, Masoud Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title solvated molecular salt, C(6)H(9)N(2) (+)·C(7)H(4)NO(4) (−)·CH(4)O, the pyridine N atom of 2-amino-4-methyl­pyridine is protonated and one carboxyl group of pyridine-2,6-dicarb­oxy­lic acid is deprotonated. The dihedral angles between the –CO(2) and –COH groups and the pyridine ring are 0.65 (13) and 7.4°. The crystal packing is stabilized by inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. International Union of Crystallography 2010-12-08 /pmc/articles/PMC3050251/ /pubmed/21522764 http://dx.doi.org/10.1107/S1600536810050245 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Aghabozorg, Hossein
Mofidi Rouchi, Azadeh
Mirzaei, Masoud
Notash, Behrouz
2-Amino-4-methyl­pyridinium 6-carb­oxy­pyridine-2-carboxyl­ate methanol monosolvate
title 2-Amino-4-methyl­pyridinium 6-carb­oxy­pyridine-2-carboxyl­ate methanol monosolvate
title_full 2-Amino-4-methyl­pyridinium 6-carb­oxy­pyridine-2-carboxyl­ate methanol monosolvate
title_fullStr 2-Amino-4-methyl­pyridinium 6-carb­oxy­pyridine-2-carboxyl­ate methanol monosolvate
title_full_unstemmed 2-Amino-4-methyl­pyridinium 6-carb­oxy­pyridine-2-carboxyl­ate methanol monosolvate
title_short 2-Amino-4-methyl­pyridinium 6-carb­oxy­pyridine-2-carboxyl­ate methanol monosolvate
title_sort 2-amino-4-methyl­pyridinium 6-carb­oxy­pyridine-2-carboxyl­ate methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050251/
https://www.ncbi.nlm.nih.gov/pubmed/21522764
http://dx.doi.org/10.1107/S1600536810050245
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AT mirzaeimasoud 2amino4methylpyridinium6carboxypyridine2carboxylatemethanolmonosolvate
AT notashbehrouz 2amino4methylpyridinium6carboxypyridine2carboxylatemethanolmonosolvate

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