Bis(1,3-dimethyl-1,3-diazinan-2-one)dinitratodioxidouranium(VI)

The title compound, [U(NO(3))(2)O(2)(C(6)H(12)N(2)O)(2)], exhibits a hexa­gonal–bipyramidal geometry around the U(VI) ion, which is situated on an inversion centre and coordinated by two oxide ligands in the axial positions, and four O atoms from two bidentate NO(3) (−) and two O atoms from two 1,3-...

Descripción completa

Detalles Bibliográficos
Autores principales: Suzuki, Tomoya, Kawasaki, Takeshi, Ikeda, Yasuhisa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050256/
https://www.ncbi.nlm.nih.gov/pubmed/21522544
http://dx.doi.org/10.1107/S1600536810049883
Descripción
Sumario:The title compound, [U(NO(3))(2)O(2)(C(6)H(12)N(2)O)(2)], exhibits a hexa­gonal–bipyramidal geometry around the U(VI) ion, which is situated on an inversion centre and coordinated by two oxide ligands in the axial positions, and four O atoms from two bidentate NO(3) (−) and two O atoms from two 1,3-dimethyl-1,3-diazinan-2-one (DMPU) ligands in the equatorial plane. These ligands are located in trans positions. The –(CH(2))(3)– moiety in the DMPU ligand is disordered over two positions in a 0.786 (11):0.214 (11) ratio.

Ejemplares similares