cis-Dichloridotetra­kis­(trimethyl­phosphane-κP)ruthenium(II) benzene disolvate

The title compound, cis-[RuCl(2)(C(3)H(9)P)(4)]·2C(6)H(6), contains a complex mol­ecule with a crystallographic mirror plane passing through the Ru(II) atom, the two cis-disposed Cl ligands and two P atoms of the two cis-disposed P(CH(3))(3) ligands. The Ru(II) atom adopts a distorted octa­hedral Ru...

Descripción completa

Detalles Bibliográficos
Autores principales: Fu, Chen, Wen, Ting Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050259/
https://www.ncbi.nlm.nih.gov/pubmed/21522541
http://dx.doi.org/10.1107/S1600536810049706
_version_ 1782199322023034880
author Fu, Chen
Wen, Ting Bin
author_facet Fu, Chen
Wen, Ting Bin
author_sort Fu, Chen
collection PubMed
description The title compound, cis-[RuCl(2)(C(3)H(9)P)(4)]·2C(6)H(6), contains a complex mol­ecule with a crystallographic mirror plane passing through the Ru(II) atom, the two cis-disposed Cl ligands and two P atoms of the two cis-disposed P(CH(3))(3) ligands. The Ru(II) atom adopts a distorted octa­hedral RuCl(2)P(4) coordination geometry with the two trans-disposed P atoms occupying the axial positions. The packing of the structure is accomplished through non-classical C—H⋯Cl hydrogen bonds between the benzene solvent mol­ecule and one of the Cl ligands.
format Text
id pubmed-3050259
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30502592011-04-26 cis-Dichloridotetra­kis­(trimethyl­phosphane-κP)ruthenium(II) benzene disolvate Fu, Chen Wen, Ting Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, cis-[RuCl(2)(C(3)H(9)P)(4)]·2C(6)H(6), contains a complex mol­ecule with a crystallographic mirror plane passing through the Ru(II) atom, the two cis-disposed Cl ligands and two P atoms of the two cis-disposed P(CH(3))(3) ligands. The Ru(II) atom adopts a distorted octa­hedral RuCl(2)P(4) coordination geometry with the two trans-disposed P atoms occupying the axial positions. The packing of the structure is accomplished through non-classical C—H⋯Cl hydrogen bonds between the benzene solvent mol­ecule and one of the Cl ligands. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050259/ /pubmed/21522541 http://dx.doi.org/10.1107/S1600536810049706 Text en © Fu and Wen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fu, Chen
Wen, Ting Bin
cis-Dichloridotetra­kis­(trimethyl­phosphane-κP)ruthenium(II) benzene disolvate
title cis-Dichloridotetra­kis­(trimethyl­phosphane-κP)ruthenium(II) benzene disolvate
title_full cis-Dichloridotetra­kis­(trimethyl­phosphane-κP)ruthenium(II) benzene disolvate
title_fullStr cis-Dichloridotetra­kis­(trimethyl­phosphane-κP)ruthenium(II) benzene disolvate
title_full_unstemmed cis-Dichloridotetra­kis­(trimethyl­phosphane-κP)ruthenium(II) benzene disolvate
title_short cis-Dichloridotetra­kis­(trimethyl­phosphane-κP)ruthenium(II) benzene disolvate
title_sort cis-dichloridotetra­kis­(trimethyl­phosphane-κp)ruthenium(ii) benzene disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050259/
https://www.ncbi.nlm.nih.gov/pubmed/21522541
http://dx.doi.org/10.1107/S1600536810049706
work_keys_str_mv AT fuchen cisdichloridotetrakistrimethylphosphanekprutheniumiibenzenedisolvate
AT wentingbin cisdichloridotetrakistrimethylphosphanekprutheniumiibenzenedisolvate

Ejemplares similares