Dichlorido(N,N′-diisopropyl­piperidine-1-carboximidamidato-κ(2) N,N′)titanium(IV)

In the mononuclear title complex, [Ti(C(12)H(24)N(3))(2)Cl(2)], the Ti(IV) ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N′,N′′-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral angles between...

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Detalles Bibliográficos
Autores principales: Wang, Mei, Yao, Ying-Ming, Zhang, Yong, Zhang, Zhen-Qin, Shi, Li-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050264/
https://www.ncbi.nlm.nih.gov/pubmed/21522536
http://dx.doi.org/10.1107/S1600536810053262
Descripción
Sumario:In the mononuclear title complex, [Ti(C(12)H(24)N(3))(2)Cl(2)], the Ti(IV) ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N′,N′′-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral angles between the piperidine groups and the NCN chelate rings are 51.5 (1) and 52.3 (1)°.

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