Dichlorido(N,N′-diisopropyl­piperidine-1-carboximidamidato-κ(2) N,N′)titanium(IV)

In the mononuclear title complex, [Ti(C(12)H(24)N(3))(2)Cl(2)], the Ti(IV) ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N′,N′′-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral angles between...

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Detalles Bibliográficos
Autores principales: Wang, Mei, Yao, Ying-Ming, Zhang, Yong, Zhang, Zhen-Qin, Shi, Li-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050264/
https://www.ncbi.nlm.nih.gov/pubmed/21522536
http://dx.doi.org/10.1107/S1600536810053262
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author Wang, Mei
Yao, Ying-Ming
Zhang, Yong
Zhang, Zhen-Qin
Shi, Li-Ying
author_facet Wang, Mei
Yao, Ying-Ming
Zhang, Yong
Zhang, Zhen-Qin
Shi, Li-Ying
author_sort Wang, Mei
collection PubMed
description In the mononuclear title complex, [Ti(C(12)H(24)N(3))(2)Cl(2)], the Ti(IV) ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N′,N′′-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral angles between the piperidine groups and the NCN chelate rings are 51.5 (1) and 52.3 (1)°.
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spelling pubmed-30502642011-04-26 Dichlorido(N,N′-diisopropyl­piperidine-1-carboximidamidato-κ(2) N,N′)titanium(IV) Wang, Mei Yao, Ying-Ming Zhang, Yong Zhang, Zhen-Qin Shi, Li-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Ti(C(12)H(24)N(3))(2)Cl(2)], the Ti(IV) ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N′,N′′-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral angles between the piperidine groups and the NCN chelate rings are 51.5 (1) and 52.3 (1)°. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050264/ /pubmed/21522536 http://dx.doi.org/10.1107/S1600536810053262 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Mei
Yao, Ying-Ming
Zhang, Yong
Zhang, Zhen-Qin
Shi, Li-Ying
Dichlorido(N,N′-diisopropyl­piperidine-1-carboximidamidato-κ(2) N,N′)titanium(IV)
title Dichlorido(N,N′-diisopropyl­piperidine-1-carboximidamidato-κ(2) N,N′)titanium(IV)
title_full Dichlorido(N,N′-diisopropyl­piperidine-1-carboximidamidato-κ(2) N,N′)titanium(IV)
title_fullStr Dichlorido(N,N′-diisopropyl­piperidine-1-carboximidamidato-κ(2) N,N′)titanium(IV)
title_full_unstemmed Dichlorido(N,N′-diisopropyl­piperidine-1-carboximidamidato-κ(2) N,N′)titanium(IV)
title_short Dichlorido(N,N′-diisopropyl­piperidine-1-carboximidamidato-κ(2) N,N′)titanium(IV)
title_sort dichlorido(n,n′-diisopropyl­piperidine-1-carboximidamidato-κ(2) n,n′)titanium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050264/
https://www.ncbi.nlm.nih.gov/pubmed/21522536
http://dx.doi.org/10.1107/S1600536810053262
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