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Aqua{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)nickel(II)
In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N′,N′′-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water O atom in a distorted octahedral geometry. Intramolecular C—H⋯N and C—H⋯O hydrogen bonds occur. In the crysta...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050266/ https://www.ncbi.nlm.nih.gov/pubmed/21522521 http://dx.doi.org/10.1107/S1600536810052578 |
| _version_ | 1782199323705999360 |
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| author | Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
| author_facet | Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
| author_sort | Suleiman Gwaram, Nura |
| collection | PubMed |
| description | In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N′,N′′-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water O atom in a distorted octahedral geometry. Intramolecular C—H⋯N and C—H⋯O hydrogen bonds occur. In the crystal, O—H⋯S, O—H⋯O and C—H⋯S hydrogen bonds link adjacent molecules into layers parallel to the ac plane. |
| format | Text |
| id | pubmed-3050266 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30502662011-04-26 Aqua{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)nickel(II) Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N′,N′′-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water O atom in a distorted octahedral geometry. Intramolecular C—H⋯N and C—H⋯O hydrogen bonds occur. In the crystal, O—H⋯S, O—H⋯O and C—H⋯S hydrogen bonds link adjacent molecules into layers parallel to the ac plane. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050266/ /pubmed/21522521 http://dx.doi.org/10.1107/S1600536810052578 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Aqua{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)nickel(II) |
| title | Aqua{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)nickel(II) |
| title_full | Aqua{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)nickel(II) |
| title_fullStr | Aqua{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)nickel(II) |
| title_full_unstemmed | Aqua{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)nickel(II) |
| title_short | Aqua{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)nickel(II) |
| title_sort | aqua{2-morpholino-n-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
n,n′,n′′}bis(thiocyanato-κn)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050266/ https://www.ncbi.nlm.nih.gov/pubmed/21522521 http://dx.doi.org/10.1107/S1600536810052578 |
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