Bis(2,4-dimeth­oxy­phen­yl)(phen­yl)phosphine selenide

In the title mol­ecule, C(22)H(23)O(4)PSe, the P atom has a distorted tetra­hedral environment formed by the selenide atom [P=Se = 2.1219 (5) Å] and three aryl rings. The orientations of the meth­oxy groups in the two 2,4-dimeth­oxy­phenyl ligands are distinct, as seen from the torsion angles: C—C—O...

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Detalles Bibliográficos
Autor principal: Muller, Alfred
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050267/
https://www.ncbi.nlm.nih.gov/pubmed/21522806
http://dx.doi.org/10.1107/S1600536810049366
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author Muller, Alfred
author_facet Muller, Alfred
author_sort Muller, Alfred
collection PubMed
description In the title mol­ecule, C(22)H(23)O(4)PSe, the P atom has a distorted tetra­hedral environment formed by the selenide atom [P=Se = 2.1219 (5) Å] and three aryl rings. The orientations of the meth­oxy groups in the two 2,4-dimeth­oxy­phenyl ligands are distinct, as seen from the torsion angles: C—C—O—C = 14.7 (3) and 175.97 (17)° in one ligand, and −9.1 (2) and 5.1 (3)° in the other. In the crystal, weak inter­molecular C—H⋯Se inter­actions link the mol­ecules into zigzag chains propagated in [010].
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spelling pubmed-30502672011-04-26 Bis(2,4-dimeth­oxy­phen­yl)(phen­yl)phosphine selenide Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(22)H(23)O(4)PSe, the P atom has a distorted tetra­hedral environment formed by the selenide atom [P=Se = 2.1219 (5) Å] and three aryl rings. The orientations of the meth­oxy groups in the two 2,4-dimeth­oxy­phenyl ligands are distinct, as seen from the torsion angles: C—C—O—C = 14.7 (3) and 175.97 (17)° in one ligand, and −9.1 (2) and 5.1 (3)° in the other. In the crystal, weak inter­molecular C—H⋯Se inter­actions link the mol­ecules into zigzag chains propagated in [010]. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050267/ /pubmed/21522806 http://dx.doi.org/10.1107/S1600536810049366 Text en © Alfred Muller 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Muller, Alfred
Bis(2,4-dimeth­oxy­phen­yl)(phen­yl)phosphine selenide
title Bis(2,4-dimeth­oxy­phen­yl)(phen­yl)phosphine selenide
title_full Bis(2,4-dimeth­oxy­phen­yl)(phen­yl)phosphine selenide
title_fullStr Bis(2,4-dimeth­oxy­phen­yl)(phen­yl)phosphine selenide
title_full_unstemmed Bis(2,4-dimeth­oxy­phen­yl)(phen­yl)phosphine selenide
title_short Bis(2,4-dimeth­oxy­phen­yl)(phen­yl)phosphine selenide
title_sort bis(2,4-dimeth­oxy­phen­yl)(phen­yl)phosphine selenide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050267/
https://www.ncbi.nlm.nih.gov/pubmed/21522806
http://dx.doi.org/10.1107/S1600536810049366
work_keys_str_mv AT mulleralfred bis24dimethoxyphenylphenylphosphineselenide

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