16-[(E)-4-Bromo­benzyl­idene]-13-(4-bromo­phen­yl)-2-hy­droxy-11-methyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione

In the title pyrrolidine compound, C(30)H(24)Br(2)N(2)O(3), the two fused pyrrolidine rings adopt envelope and twisted conformations, whereas the piperidine ring adopts an envelope conformation. The essentially planar 2,3-dihydro­indanone unit [maximum deviation = −0.0163 (19) Å] is inclined at inte...

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Autores principales: Kumar, Raju Suresh, Osman, Hasnah, Perumal, Subbu, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050270/
https://www.ncbi.nlm.nih.gov/pubmed/21522647
http://dx.doi.org/10.1107/S1600536810051585
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author Kumar, Raju Suresh
Osman, Hasnah
Perumal, Subbu
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Kumar, Raju Suresh
Osman, Hasnah
Perumal, Subbu
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Kumar, Raju Suresh
collection PubMed
description In the title pyrrolidine compound, C(30)H(24)Br(2)N(2)O(3), the two fused pyrrolidine rings adopt envelope and twisted conformations, whereas the piperidine ring adopts an envelope conformation. The essentially planar 2,3-dihydro­indanone unit [maximum deviation = −0.0163 (19) Å] is inclined at inter­planar angles of 14.29 (9) and 61.07 (9)° to the two benzene rings. In the crystal, adjacent mol­ecules are linked into dimers by inter­molecular O—H⋯N and C—H⋯O hydrogen bonds. Short inter­molecular Br⋯Br inter­actions [3.5140 (6) Å] further inter­connect these dimers into double dimeric columns along the b axis.
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spelling pubmed-30502702011-04-26 16-[(E)-4-Bromo­benzyl­idene]-13-(4-bromo­phen­yl)-2-hy­droxy-11-methyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione Kumar, Raju Suresh Osman, Hasnah Perumal, Subbu Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title pyrrolidine compound, C(30)H(24)Br(2)N(2)O(3), the two fused pyrrolidine rings adopt envelope and twisted conformations, whereas the piperidine ring adopts an envelope conformation. The essentially planar 2,3-dihydro­indanone unit [maximum deviation = −0.0163 (19) Å] is inclined at inter­planar angles of 14.29 (9) and 61.07 (9)° to the two benzene rings. In the crystal, adjacent mol­ecules are linked into dimers by inter­molecular O—H⋯N and C—H⋯O hydrogen bonds. Short inter­molecular Br⋯Br inter­actions [3.5140 (6) Å] further inter­connect these dimers into double dimeric columns along the b axis. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050270/ /pubmed/21522647 http://dx.doi.org/10.1107/S1600536810051585 Text en © Kumar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, Raju Suresh
Osman, Hasnah
Perumal, Subbu
Goh, Jia Hao
Fun, Hoong-Kun
16-[(E)-4-Bromo­benzyl­idene]-13-(4-bromo­phen­yl)-2-hy­droxy-11-methyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title 16-[(E)-4-Bromo­benzyl­idene]-13-(4-bromo­phen­yl)-2-hy­droxy-11-methyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_full 16-[(E)-4-Bromo­benzyl­idene]-13-(4-bromo­phen­yl)-2-hy­droxy-11-methyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_fullStr 16-[(E)-4-Bromo­benzyl­idene]-13-(4-bromo­phen­yl)-2-hy­droxy-11-methyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_full_unstemmed 16-[(E)-4-Bromo­benzyl­idene]-13-(4-bromo­phen­yl)-2-hy­droxy-11-methyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_short 16-[(E)-4-Bromo­benzyl­idene]-13-(4-bromo­phen­yl)-2-hy­droxy-11-methyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_sort 16-[(e)-4-bromo­benzyl­idene]-13-(4-bromo­phen­yl)-2-hy­droxy-11-methyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050270/
https://www.ncbi.nlm.nih.gov/pubmed/21522647
http://dx.doi.org/10.1107/S1600536810051585
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