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The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4))

Crystals of β-Zn(3)(BO(3))(PO(4)) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure ar...

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Detalles Bibliográficos
Autores principales: Zhang, Erpan, Zhao, Sangen, Zhang, Jianxiu, Fu, Peizhen, Yao, Jiyong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050272/
https://www.ncbi.nlm.nih.gov/pubmed/21522511
http://dx.doi.org/10.1107/S1600536810051871
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author Zhang, Erpan
Zhao, Sangen
Zhang, Jianxiu
Fu, Peizhen
Yao, Jiyong
author_facet Zhang, Erpan
Zhao, Sangen
Zhang, Jianxiu
Fu, Peizhen
Yao, Jiyong
author_sort Zhang, Erpan
collection PubMed
description Crystals of β-Zn(3)(BO(3))(PO(4)) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure are isolated BO(3) triangles and PO(4) tetra­hedra, which are bridged by ZnO(4) tetra­hedra or ZnO(5) trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure. Some significant structural differences between the β-polymorph and the α-polymorph are discussed.
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spelling pubmed-30502722011-04-26 The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)) Zhang, Erpan Zhao, Sangen Zhang, Jianxiu Fu, Peizhen Yao, Jiyong Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Crystals of β-Zn(3)(BO(3))(PO(4)) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure are isolated BO(3) triangles and PO(4) tetra­hedra, which are bridged by ZnO(4) tetra­hedra or ZnO(5) trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure. Some significant structural differences between the β-polymorph and the α-polymorph are discussed. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050272/ /pubmed/21522511 http://dx.doi.org/10.1107/S1600536810051871 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zhang, Erpan
Zhao, Sangen
Zhang, Jianxiu
Fu, Peizhen
Yao, Jiyong
The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4))
title The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4))
title_full The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4))
title_fullStr The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4))
title_full_unstemmed The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4))
title_short The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4))
title_sort β-modification of trizinc borate phosphate, zn(3)(bo(3))(po(4))
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050272/
https://www.ncbi.nlm.nih.gov/pubmed/21522511
http://dx.doi.org/10.1107/S1600536810051871
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