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The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4))
Crystals of β-Zn(3)(BO(3))(PO(4)) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure ar...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050272/ https://www.ncbi.nlm.nih.gov/pubmed/21522511 http://dx.doi.org/10.1107/S1600536810051871 |
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author | Zhang, Erpan Zhao, Sangen Zhang, Jianxiu Fu, Peizhen Yao, Jiyong |
author_facet | Zhang, Erpan Zhao, Sangen Zhang, Jianxiu Fu, Peizhen Yao, Jiyong |
author_sort | Zhang, Erpan |
collection | PubMed |
description | Crystals of β-Zn(3)(BO(3))(PO(4)) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure are isolated BO(3) triangles and PO(4) tetrahedra, which are bridged by ZnO(4) tetrahedra or ZnO(5) trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure. Some significant structural differences between the β-polymorph and the α-polymorph are discussed. |
format | Text |
id | pubmed-3050272 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30502722011-04-26 The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)) Zhang, Erpan Zhao, Sangen Zhang, Jianxiu Fu, Peizhen Yao, Jiyong Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Crystals of β-Zn(3)(BO(3))(PO(4)) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure are isolated BO(3) triangles and PO(4) tetrahedra, which are bridged by ZnO(4) tetrahedra or ZnO(5) trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure. Some significant structural differences between the β-polymorph and the α-polymorph are discussed. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050272/ /pubmed/21522511 http://dx.doi.org/10.1107/S1600536810051871 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Zhang, Erpan Zhao, Sangen Zhang, Jianxiu Fu, Peizhen Yao, Jiyong The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)) |
title | The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)) |
title_full | The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)) |
title_fullStr | The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)) |
title_full_unstemmed | The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)) |
title_short | The β-modification of trizinc borate phosphate, Zn(3)(BO(3))(PO(4)) |
title_sort | β-modification of trizinc borate phosphate, zn(3)(bo(3))(po(4)) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050272/ https://www.ncbi.nlm.nih.gov/pubmed/21522511 http://dx.doi.org/10.1107/S1600536810051871 |
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