{5,5′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)

In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, mol­ecules are connected through inter­molecular C—H⋯O hydrogen bond,...

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Detalles Bibliográficos
Autores principales: Sahraei, Atefeh, Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050280/
https://www.ncbi.nlm.nih.gov/pubmed/21522599
http://dx.doi.org/10.1107/S1600536810051834
Descripción
Sumario:In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, mol­ecules are connected through inter­molecular C—H⋯O hydrogen bond, resulting in chains extending along the c axis. The crystal structure is further stabilized by inter­molecular π–π inter­actions, with centroid–centroid distances in the range 3.3760 (15)–3.7196 (17) Å.

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