{5,5′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)

In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, mol­ecules are connected through inter­molecular C—H⋯O hydrogen bond,...

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Detalles Bibliográficos
Autores principales: Sahraei, Atefeh, Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050280/
https://www.ncbi.nlm.nih.gov/pubmed/21522599
http://dx.doi.org/10.1107/S1600536810051834
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author Sahraei, Atefeh
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_facet Sahraei, Atefeh
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_sort Sahraei, Atefeh
collection PubMed
description In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, mol­ecules are connected through inter­molecular C—H⋯O hydrogen bond, resulting in chains extending along the c axis. The crystal structure is further stabilized by inter­molecular π–π inter­actions, with centroid–centroid distances in the range 3.3760 (15)–3.7196 (17) Å.
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spelling pubmed-30502802011-04-26 {5,5′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) Sahraei, Atefeh Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, mol­ecules are connected through inter­molecular C—H⋯O hydrogen bond, resulting in chains extending along the c axis. The crystal structure is further stabilized by inter­molecular π–π inter­actions, with centroid–centroid distances in the range 3.3760 (15)–3.7196 (17) Å. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050280/ /pubmed/21522599 http://dx.doi.org/10.1107/S1600536810051834 Text en © Sahraei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sahraei, Atefeh
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
{5,5′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title {5,5′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_full {5,5′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_fullStr {5,5′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_full_unstemmed {5,5′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_short {5,5′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_sort {5,5′-dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050280/
https://www.ncbi.nlm.nih.gov/pubmed/21522599
http://dx.doi.org/10.1107/S1600536810051834
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AT kiareza 55dimethoxy2245dimethylophenylenebisnitrilomethylidynediphenolatonickelii
AT tahirmuhammadnawaz 55dimethoxy2245dimethylophenylenebisnitrilomethylidynediphenolatonickelii

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