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Bis[1-(3-cyano­benz­yl)pyridinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)

In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2−) dianion (mnt(2−) is maleonitrile­dithiolate) and one 1-(3-cyano­benz­yl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in...

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Detalles Bibliográficos
Autores principales: Xian, Hua, Duan, Hai-Bao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050285/
https://www.ncbi.nlm.nih.gov/pubmed/21522588
http://dx.doi.org/10.1107/S1600536810051263
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author Xian, Hua
Duan, Hai-Bao
author_facet Xian, Hua
Duan, Hai-Bao
author_sort Xian, Hua
collection PubMed
description In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2−) dianion (mnt(2−) is maleonitrile­dithiolate) and one 1-(3-cyano­benz­yl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in the [Ni(mnt)(2)](2−) anion is coordinated by four S atoms of two mnt(2−) ligands, and exhibits square-planar coordination geometry. In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methyl­ene C atom that links them. The crystal structure is stabilized by Coulombic inter­actions.
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spelling pubmed-30502852011-04-26 Bis[1-(3-cyano­benz­yl)pyridinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II) Xian, Hua Duan, Hai-Bao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2−) dianion (mnt(2−) is maleonitrile­dithiolate) and one 1-(3-cyano­benz­yl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in the [Ni(mnt)(2)](2−) anion is coordinated by four S atoms of two mnt(2−) ligands, and exhibits square-planar coordination geometry. In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methyl­ene C atom that links them. The crystal structure is stabilized by Coulombic inter­actions. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050285/ /pubmed/21522588 http://dx.doi.org/10.1107/S1600536810051263 Text en © Xian and Duan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xian, Hua
Duan, Hai-Bao
Bis[1-(3-cyano­benz­yl)pyridinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title Bis[1-(3-cyano­benz­yl)pyridinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_full Bis[1-(3-cyano­benz­yl)pyridinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_fullStr Bis[1-(3-cyano­benz­yl)pyridinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_full_unstemmed Bis[1-(3-cyano­benz­yl)pyridinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_short Bis[1-(3-cyano­benz­yl)pyridinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_sort bis[1-(3-cyano­benz­yl)pyridinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050285/
https://www.ncbi.nlm.nih.gov/pubmed/21522588
http://dx.doi.org/10.1107/S1600536810051263
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AT duanhaibao bis13cyanobenzylpyridiniumbis12dicyanoethene12dithiolatonickelateii