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Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II)
In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2−) dianion (mnt(2−) is maleonitriledithiolate) and one 1-(3-cyanobenzyl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050285/ https://www.ncbi.nlm.nih.gov/pubmed/21522588 http://dx.doi.org/10.1107/S1600536810051263 |
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author | Xian, Hua Duan, Hai-Bao |
author_facet | Xian, Hua Duan, Hai-Bao |
author_sort | Xian, Hua |
collection | PubMed |
description | In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2−) dianion (mnt(2−) is maleonitriledithiolate) and one 1-(3-cyanobenzyl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in the [Ni(mnt)(2)](2−) anion is coordinated by four S atoms of two mnt(2−) ligands, and exhibits square-planar coordination geometry. In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methylene C atom that links them. The crystal structure is stabilized by Coulombic interactions. |
format | Text |
id | pubmed-3050285 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30502852011-04-26 Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II) Xian, Hua Duan, Hai-Bao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2−) dianion (mnt(2−) is maleonitriledithiolate) and one 1-(3-cyanobenzyl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in the [Ni(mnt)(2)](2−) anion is coordinated by four S atoms of two mnt(2−) ligands, and exhibits square-planar coordination geometry. In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methylene C atom that links them. The crystal structure is stabilized by Coulombic interactions. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050285/ /pubmed/21522588 http://dx.doi.org/10.1107/S1600536810051263 Text en © Xian and Duan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xian, Hua Duan, Hai-Bao Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II) |
title | Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II) |
title_full | Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II) |
title_fullStr | Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II) |
title_full_unstemmed | Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II) |
title_short | Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II) |
title_sort | bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050285/ https://www.ncbi.nlm.nih.gov/pubmed/21522588 http://dx.doi.org/10.1107/S1600536810051263 |
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