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Chlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ(3) N,N′,O)copper(II)
In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N′,O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent molecules are linked via C—H⋯Cl and C—H⋯O interactions, forming infinite laye...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050288/ https://www.ncbi.nlm.nih.gov/pubmed/21522575 http://dx.doi.org/10.1107/S1600536810051160 |
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| author | Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
| author_facet | Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
| author_sort | Ikmal Hisham, Nurul Azimah |
| collection | PubMed |
| description | In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N′,O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent molecules are linked via C—H⋯Cl and C—H⋯O interactions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined crystal [twin ratio 0.777 (3):0.223 (3)]. |
| format | Text |
| id | pubmed-3050288 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30502882011-04-26 Chlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ(3) N,N′,O)copper(II) Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N′,O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent molecules are linked via C—H⋯Cl and C—H⋯O interactions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined crystal [twin ratio 0.777 (3):0.223 (3)]. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050288/ /pubmed/21522575 http://dx.doi.org/10.1107/S1600536810051160 Text en © Ikmal Hisham et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Chlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ(3) N,N′,O)copper(II) |
| title | Chlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ(3)
N,N′,O)copper(II) |
| title_full | Chlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ(3)
N,N′,O)copper(II) |
| title_fullStr | Chlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ(3)
N,N′,O)copper(II) |
| title_full_unstemmed | Chlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ(3)
N,N′,O)copper(II) |
| title_short | Chlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ(3)
N,N′,O)copper(II) |
| title_sort | chlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ(3)
n,n′,o)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050288/ https://www.ncbi.nlm.nih.gov/pubmed/21522575 http://dx.doi.org/10.1107/S1600536810051160 |
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