catena-Poly[triethyl­ammonium [[triphenyl­tin(IV)]-μ-3,3′-dihydroxy-4,4′-methyl­ene­di-2-naphtho­ato]]

The title compound, {(C(6)H(16)N)[Sn(C(6)H(5))(3)(C(23)H(14)O(6))]}(n), has an infinite chain structure, formed through monodentate carboxyl­ate groups of the pamoic acid anion. The anion bridges two symmetry-related Sn(IV) ions and the resulting polymeric chains are parallel to [201] in the crystal...

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Detalles Bibliográficos
Autores principales: Liu, Lijun, Gong, Shuwen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050292/
https://www.ncbi.nlm.nih.gov/pubmed/21522533
http://dx.doi.org/10.1107/S1600536810052402
Descripción
Sumario:The title compound, {(C(6)H(16)N)[Sn(C(6)H(5))(3)(C(23)H(14)O(6))]}(n), has an infinite chain structure, formed through monodentate carboxyl­ate groups of the pamoic acid anion. The anion bridges two symmetry-related Sn(IV) ions and the resulting polymeric chains are parallel to [201] in the crystal. Et(3)NH(+) cations are inserted between the chains. The coordination of the Sn(IV) atom is completed by three phenyl ligands, giving a distorted trigonal–bipyramidal geometry.

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