2-[3-((Z)-2-{4-[Bis(2-chloro­eth­yl)amino]­phen­yl}ethen­yl)-5,5-dimethyl­cyclo­hex-2-en-1-yl­idene]propane­dinitrile

The highly conjugated title compound, C(23)H(25)Cl(2)N(3), is nearly planar (the mean deviation from the plane being 0.049 Å), except for the –C(CH(3))(2) group on the cyclo­hexene ring and the two CH(2)Cl groups. The cyclo­hexene ring has an envelope configuration. In the crystal, the packing is st...

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Detalles Bibliográficos
Autores principales: Liu, Li, Shao, Ying, Shi, Jie-Ping, Hu, Hong-Wen, Lu, Guo-Yuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050295/
https://www.ncbi.nlm.nih.gov/pubmed/21522635
http://dx.doi.org/10.1107/S1600536810051068
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author Liu, Li
Shao, Ying
Shi, Jie-Ping
Hu, Hong-Wen
Lu, Guo-Yuan
author_facet Liu, Li
Shao, Ying
Shi, Jie-Ping
Hu, Hong-Wen
Lu, Guo-Yuan
author_sort Liu, Li
collection PubMed
description The highly conjugated title compound, C(23)H(25)Cl(2)N(3), is nearly planar (the mean deviation from the plane being 0.049 Å), except for the –C(CH(3))(2) group on the cyclo­hexene ring and the two CH(2)Cl groups. The cyclo­hexene ring has an envelope configuration. In the crystal, the packing is stabilized by C—H⋯Cl inter­actions and C—H⋯π inter­actions involving the benzene ring.
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spelling pubmed-30502952011-04-26 2-[3-((Z)-2-{4-[Bis(2-chloro­eth­yl)amino]­phen­yl}ethen­yl)-5,5-dimethyl­cyclo­hex-2-en-1-yl­idene]propane­dinitrile Liu, Li Shao, Ying Shi, Jie-Ping Hu, Hong-Wen Lu, Guo-Yuan Acta Crystallogr Sect E Struct Rep Online Organic Papers The highly conjugated title compound, C(23)H(25)Cl(2)N(3), is nearly planar (the mean deviation from the plane being 0.049 Å), except for the –C(CH(3))(2) group on the cyclo­hexene ring and the two CH(2)Cl groups. The cyclo­hexene ring has an envelope configuration. In the crystal, the packing is stabilized by C—H⋯Cl inter­actions and C—H⋯π inter­actions involving the benzene ring. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050295/ /pubmed/21522635 http://dx.doi.org/10.1107/S1600536810051068 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Li
Shao, Ying
Shi, Jie-Ping
Hu, Hong-Wen
Lu, Guo-Yuan
2-[3-((Z)-2-{4-[Bis(2-chloro­eth­yl)amino]­phen­yl}ethen­yl)-5,5-dimethyl­cyclo­hex-2-en-1-yl­idene]propane­dinitrile
title 2-[3-((Z)-2-{4-[Bis(2-chloro­eth­yl)amino]­phen­yl}ethen­yl)-5,5-dimethyl­cyclo­hex-2-en-1-yl­idene]propane­dinitrile
title_full 2-[3-((Z)-2-{4-[Bis(2-chloro­eth­yl)amino]­phen­yl}ethen­yl)-5,5-dimethyl­cyclo­hex-2-en-1-yl­idene]propane­dinitrile
title_fullStr 2-[3-((Z)-2-{4-[Bis(2-chloro­eth­yl)amino]­phen­yl}ethen­yl)-5,5-dimethyl­cyclo­hex-2-en-1-yl­idene]propane­dinitrile
title_full_unstemmed 2-[3-((Z)-2-{4-[Bis(2-chloro­eth­yl)amino]­phen­yl}ethen­yl)-5,5-dimethyl­cyclo­hex-2-en-1-yl­idene]propane­dinitrile
title_short 2-[3-((Z)-2-{4-[Bis(2-chloro­eth­yl)amino]­phen­yl}ethen­yl)-5,5-dimethyl­cyclo­hex-2-en-1-yl­idene]propane­dinitrile
title_sort 2-[3-((z)-2-{4-[bis(2-chloro­eth­yl)amino]­phen­yl}ethen­yl)-5,5-dimethyl­cyclo­hex-2-en-1-yl­idene]propane­dinitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050295/
https://www.ncbi.nlm.nih.gov/pubmed/21522635
http://dx.doi.org/10.1107/S1600536810051068
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AT shijieping 23z24bis2chloroethylaminophenylethenyl55dimethylcyclohex2en1ylidenepropanedinitrile
AT huhongwen 23z24bis2chloroethylaminophenylethenyl55dimethylcyclohex2en1ylidenepropanedinitrile
AT luguoyuan 23z24bis2chloroethylaminophenylethenyl55dimethylcyclohex2en1ylidenepropanedinitrile

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