Chlorido(η(5)-cyclo­penta­dien­yl)[(4a,4b,8a,9,9a-η)-fluoren­yl](fluorenyl-κC (9))zirconium(IV) toluene solvate

In the title compound, [Zr(C(5)H(5))(C(13)H(9))(2)Cl]·C(7)H(8), the Zr(IV) atom is coordinated by a Cl atom, a cyclo­penta­dienyl (Cp) ligand [Zr–centroid (Cp) = 2.199 (3) Å] and two fluorenyl ligands (Fl) [Zr–centroid (Fl) = 2.273 (2) Å and Zr—CH from fluorenyl = 2.355 (2) Å] in a distorted tetra­g...

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Autores principales: Łapczuk-Krygier, Agnieszka, Ponikiewski, Łukasz, Pikies, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050299/
https://www.ncbi.nlm.nih.gov/pubmed/21522572
http://dx.doi.org/10.1107/S1600536810050816
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author Łapczuk-Krygier, Agnieszka
Ponikiewski, Łukasz
Pikies, Jerzy
author_facet Łapczuk-Krygier, Agnieszka
Ponikiewski, Łukasz
Pikies, Jerzy
author_sort Łapczuk-Krygier, Agnieszka
collection PubMed
description In the title compound, [Zr(C(5)H(5))(C(13)H(9))(2)Cl]·C(7)H(8), the Zr(IV) atom is coordinated by a Cl atom, a cyclo­penta­dienyl (Cp) ligand [Zr–centroid (Cp) = 2.199 (3) Å] and two fluorenyl ligands (Fl) [Zr–centroid (Fl) = 2.273 (2) Å and Zr—CH from fluorenyl = 2.355 (2) Å] in a distorted tetra­gonal geometry. The dihedral angles between the mean planes of the fluorenyl ring systems and the Cp ring are 36.62 (6)° for the η(1)-coordinated fluorenyl and 52.85 (6)° for the η(5)-coordinated fluorenyl, while the dihedral angle between the mean planes of the two fluorenyl ring systems is 76.18 (7)°.
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spelling pubmed-30502992011-04-26 Chlorido(η(5)-cyclo­penta­dien­yl)[(4a,4b,8a,9,9a-η)-fluoren­yl](fluorenyl-κC (9))zirconium(IV) toluene solvate Łapczuk-Krygier, Agnieszka Ponikiewski, Łukasz Pikies, Jerzy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zr(C(5)H(5))(C(13)H(9))(2)Cl]·C(7)H(8), the Zr(IV) atom is coordinated by a Cl atom, a cyclo­penta­dienyl (Cp) ligand [Zr–centroid (Cp) = 2.199 (3) Å] and two fluorenyl ligands (Fl) [Zr–centroid (Fl) = 2.273 (2) Å and Zr—CH from fluorenyl = 2.355 (2) Å] in a distorted tetra­gonal geometry. The dihedral angles between the mean planes of the fluorenyl ring systems and the Cp ring are 36.62 (6)° for the η(1)-coordinated fluorenyl and 52.85 (6)° for the η(5)-coordinated fluorenyl, while the dihedral angle between the mean planes of the two fluorenyl ring systems is 76.18 (7)°. International Union of Crystallography 2010-12-08 /pmc/articles/PMC3050299/ /pubmed/21522572 http://dx.doi.org/10.1107/S1600536810050816 Text en © Łapczuk-Krygier et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Łapczuk-Krygier, Agnieszka
Ponikiewski, Łukasz
Pikies, Jerzy
Chlorido(η(5)-cyclo­penta­dien­yl)[(4a,4b,8a,9,9a-η)-fluoren­yl](fluorenyl-κC (9))zirconium(IV) toluene solvate
title Chlorido(η(5)-cyclo­penta­dien­yl)[(4a,4b,8a,9,9a-η)-fluoren­yl](fluorenyl-κC (9))zirconium(IV) toluene solvate
title_full Chlorido(η(5)-cyclo­penta­dien­yl)[(4a,4b,8a,9,9a-η)-fluoren­yl](fluorenyl-κC (9))zirconium(IV) toluene solvate
title_fullStr Chlorido(η(5)-cyclo­penta­dien­yl)[(4a,4b,8a,9,9a-η)-fluoren­yl](fluorenyl-κC (9))zirconium(IV) toluene solvate
title_full_unstemmed Chlorido(η(5)-cyclo­penta­dien­yl)[(4a,4b,8a,9,9a-η)-fluoren­yl](fluorenyl-κC (9))zirconium(IV) toluene solvate
title_short Chlorido(η(5)-cyclo­penta­dien­yl)[(4a,4b,8a,9,9a-η)-fluoren­yl](fluorenyl-κC (9))zirconium(IV) toluene solvate
title_sort chlorido(η(5)-cyclo­penta­dien­yl)[(4a,4b,8a,9,9a-η)-fluoren­yl](fluorenyl-κc (9))zirconium(iv) toluene solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050299/
https://www.ncbi.nlm.nih.gov/pubmed/21522572
http://dx.doi.org/10.1107/S1600536810050816
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AT ponikiewskiłukasz chloridoē5cyclopentadienyl4a4b8a99aēfluorenylfluorenylkc9zirconiumivtoluenesolvate
AT pikiesjerzy chloridoē5cyclopentadienyl4a4b8a99aēfluorenylfluorenylkc9zirconiumivtoluenesolvate

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