Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona­hydrate

The asymmetric unit of the title compound, 2C(14)H(13)N(2) (+)·2C(4)H(5)O(6) (−)·9H(2)O, contains two cations and two anions in addition to nine mol­ecules of water. Each of the hydrogen tartrate anions is hydrogen bonded to itself by translation along [100] in a head-to-tail fashion via a short hyd...

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Detalles Bibliográficos
Autores principales: Derikvand, Zohreh, Olmstead, Marilyn M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050301/
https://www.ncbi.nlm.nih.gov/pubmed/21522796
http://dx.doi.org/10.1107/S160053681005110X
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author Derikvand, Zohreh
Olmstead, Marilyn M.
author_facet Derikvand, Zohreh
Olmstead, Marilyn M.
author_sort Derikvand, Zohreh
collection PubMed
description The asymmetric unit of the title compound, 2C(14)H(13)N(2) (+)·2C(4)H(5)O(6) (−)·9H(2)O, contains two cations and two anions in addition to nine mol­ecules of water. Each of the hydrogen tartrate anions is hydrogen bonded to itself by translation along [100] in a head-to-tail fashion via a short hydrogen bond with donor–acceptor distances of 2.473 (4) and 2.496 (4) Å. A large number of inter­molecular O–H⋯O, N—H⋯O and C–H⋯O hydrogen-bonding inter­actions, as well as π–π stacking [centroid–centroid distances in the range 3.642 (3) to 3.866 (3) Å], play an important role in the crystal structure.
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spelling pubmed-30503012011-04-26 Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona­hydrate Derikvand, Zohreh Olmstead, Marilyn M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, 2C(14)H(13)N(2) (+)·2C(4)H(5)O(6) (−)·9H(2)O, contains two cations and two anions in addition to nine mol­ecules of water. Each of the hydrogen tartrate anions is hydrogen bonded to itself by translation along [100] in a head-to-tail fashion via a short hydrogen bond with donor–acceptor distances of 2.473 (4) and 2.496 (4) Å. A large number of inter­molecular O–H⋯O, N—H⋯O and C–H⋯O hydrogen-bonding inter­actions, as well as π–π stacking [centroid–centroid distances in the range 3.642 (3) to 3.866 (3) Å], play an important role in the crystal structure. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050301/ /pubmed/21522796 http://dx.doi.org/10.1107/S160053681005110X Text en © Derikvand and Olmstead 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Derikvand, Zohreh
Olmstead, Marilyn M.
Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona­hydrate
title Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona­hydrate
title_full Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona­hydrate
title_fullStr Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona­hydrate
title_full_unstemmed Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona­hydrate
title_short Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona­hydrate
title_sort bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (s,s)-tartrate nona­hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050301/
https://www.ncbi.nlm.nih.gov/pubmed/21522796
http://dx.doi.org/10.1107/S160053681005110X
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AT olmsteadmarilynm bis29dimethyl110phenanthrolin1iumhydrogensstartratenonahydrate

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