catena-Poly[[bis­(dimethyl­ammonium) [cadmate(II)-bis­(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ato)]] dimethyl­formamide disolvate]

In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa­hedral CdO(6) environment, defined by four O atoms of two μ(2)-coordinated 1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ate (DCT) ligands and two O atoms...

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Detalles Bibliográficos
Autores principales: Park, Sang-Wook, Gu, Ja-Min, Kim, Youngmee, Huh, Seong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050304/
https://www.ncbi.nlm.nih.gov/pubmed/21522589
http://dx.doi.org/10.1107/S1600536810051366
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author Park, Sang-Wook
Gu, Ja-Min
Kim, Youngmee
Huh, Seong
author_facet Park, Sang-Wook
Gu, Ja-Min
Kim, Youngmee
Huh, Seong
author_sort Park, Sang-Wook
collection PubMed
description In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa­hedral CdO(6) environment, defined by four O atoms of two μ(2)-coordinated 1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ate (DCT) ligands and two O atoms of two μ(1)-coordinated DCT ligands. Both types of DCT ligands act as bridging, forming a one-dimensional polymeric structure propagating parallel to [10[Image: see text]].
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spelling pubmed-30503042011-04-26 catena-Poly[[bis­(dimethyl­ammonium) [cadmate(II)-bis­(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ato)]] dimethyl­formamide disolvate] Park, Sang-Wook Gu, Ja-Min Kim, Youngmee Huh, Seong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa­hedral CdO(6) environment, defined by four O atoms of two μ(2)-coordinated 1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ate (DCT) ligands and two O atoms of two μ(1)-coordinated DCT ligands. Both types of DCT ligands act as bridging, forming a one-dimensional polymeric structure propagating parallel to [10[Image: see text]]. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050304/ /pubmed/21522589 http://dx.doi.org/10.1107/S1600536810051366 Text en © Park et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Park, Sang-Wook
Gu, Ja-Min
Kim, Youngmee
Huh, Seong
catena-Poly[[bis­(dimethyl­ammonium) [cadmate(II)-bis­(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ato)]] dimethyl­formamide disolvate]
title catena-Poly[[bis­(dimethyl­ammonium) [cadmate(II)-bis­(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ato)]] dimethyl­formamide disolvate]
title_full catena-Poly[[bis­(dimethyl­ammonium) [cadmate(II)-bis­(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ato)]] dimethyl­formamide disolvate]
title_fullStr catena-Poly[[bis­(dimethyl­ammonium) [cadmate(II)-bis­(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ato)]] dimethyl­formamide disolvate]
title_full_unstemmed catena-Poly[[bis­(dimethyl­ammonium) [cadmate(II)-bis­(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ato)]] dimethyl­formamide disolvate]
title_short catena-Poly[[bis­(dimethyl­ammonium) [cadmate(II)-bis­(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ato)]] dimethyl­formamide disolvate]
title_sort catena-poly[[bis­(dimethyl­ammonium) [cadmate(ii)-bis­(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxyl­ato)]] dimethyl­formamide disolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050304/
https://www.ncbi.nlm.nih.gov/pubmed/21522589
http://dx.doi.org/10.1107/S1600536810051366
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