[N-Benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine]­chloridomethyl­platinum(II)

In the mononuclear title complex, [Pt(CH(3))Cl(C(25)H(23)N(2)P)], the N-benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine functions as a bidentate ligand with the pyridyl N atom and the phosphine P atom chelating the Pt(II) ion, forming a six-membered metallocycle. The Pt(II) atom adopts a square...

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Detalles Bibliográficos
Autores principales: Wang, Zhi-Wei, Qiao, Peng, Wang, Zi-Jia, Wan, Chong-Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050312/
https://www.ncbi.nlm.nih.gov/pubmed/21522558
http://dx.doi.org/10.1107/S1600536810049652
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author Wang, Zhi-Wei
Qiao, Peng
Wang, Zi-Jia
Wan, Chong-Qing
author_facet Wang, Zhi-Wei
Qiao, Peng
Wang, Zi-Jia
Wan, Chong-Qing
author_sort Wang, Zhi-Wei
collection PubMed
description In the mononuclear title complex, [Pt(CH(3))Cl(C(25)H(23)N(2)P)], the N-benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine functions as a bidentate ligand with the pyridyl N atom and the phosphine P atom chelating the Pt(II) ion, forming a six-membered metallocycle. The Pt(II) atom adopts a square-planar coordination geometry with one methyl group and one chloride ligand bonding to the metal center in a cis relationship. C—H⋯π and C—H⋯Cl inter­actions help to consolidate the packing.
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spelling pubmed-30503122011-04-26 [N-Benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine]­chloridomethyl­platinum(II) Wang, Zhi-Wei Qiao, Peng Wang, Zi-Jia Wan, Chong-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Pt(CH(3))Cl(C(25)H(23)N(2)P)], the N-benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine functions as a bidentate ligand with the pyridyl N atom and the phosphine P atom chelating the Pt(II) ion, forming a six-membered metallocycle. The Pt(II) atom adopts a square-planar coordination geometry with one methyl group and one chloride ligand bonding to the metal center in a cis relationship. C—H⋯π and C—H⋯Cl inter­actions help to consolidate the packing. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050312/ /pubmed/21522558 http://dx.doi.org/10.1107/S1600536810049652 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zhi-Wei
Qiao, Peng
Wang, Zi-Jia
Wan, Chong-Qing
[N-Benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine]­chloridomethyl­platinum(II)
title [N-Benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine]­chloridomethyl­platinum(II)
title_full [N-Benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine]­chloridomethyl­platinum(II)
title_fullStr [N-Benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine]­chloridomethyl­platinum(II)
title_full_unstemmed [N-Benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine]­chloridomethyl­platinum(II)
title_short [N-Benzyl-N-(diphenyl­phosphanylmeth­yl)pyridin-2-amine]­chloridomethyl­platinum(II)
title_sort [n-benzyl-n-(diphenyl­phosphanylmeth­yl)pyridin-2-amine]­chloridomethyl­platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050312/
https://www.ncbi.nlm.nih.gov/pubmed/21522558
http://dx.doi.org/10.1107/S1600536810049652
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