2-[(E)-(4-Methyl­phen­yl)imino­meth­yl]-6-(morpholin-4-ylmeth­yl)phenol

In the title compound, C(19)H(22)N(2)O(2), the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters Q (T), θ and ϕ of 0.5642 (18) Å, 177.32 (17) and ϕ = 10 (4)°, respectively. The two benzene rings make a dihedral angle of 42.67 (8)° with each other. An intra­...

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Autores principales: Akkurt, Mehmet, Türktekin, Sevim, Jarrahpour, Aliasghar, Sharghi, Hashem, Badrabady, Seid Ali Torabi, Aberi, Mahdi, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050317/
https://www.ncbi.nlm.nih.gov/pubmed/21522655
http://dx.doi.org/10.1107/S1600536810052311
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author Akkurt, Mehmet
Türktekin, Sevim
Jarrahpour, Aliasghar
Sharghi, Hashem
Badrabady, Seid Ali Torabi
Aberi, Mahdi
Büyükgüngör, Orhan
author_facet Akkurt, Mehmet
Türktekin, Sevim
Jarrahpour, Aliasghar
Sharghi, Hashem
Badrabady, Seid Ali Torabi
Aberi, Mahdi
Büyükgüngör, Orhan
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, C(19)H(22)N(2)O(2), the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters Q (T), θ and ϕ of 0.5642 (18) Å, 177.32 (17) and ϕ = 10 (4)°, respectively. The two benzene rings make a dihedral angle of 42.67 (8)° with each other. An intra­molecular O—H⋯N hydrogen bond helps to stabilize the mol­ecular conformation. Aromatic C—H⋯π inter­actions and π–π stacking inter­actions [centroid–centroid distance = 3.6155 (15) Å] between the benzene rings contribute to the stabilization of the crystal structure.
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spelling pubmed-30503172011-04-26 2-[(E)-(4-Methyl­phen­yl)imino­meth­yl]-6-(morpholin-4-ylmeth­yl)phenol Akkurt, Mehmet Türktekin, Sevim Jarrahpour, Aliasghar Sharghi, Hashem Badrabady, Seid Ali Torabi Aberi, Mahdi Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(22)N(2)O(2), the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters Q (T), θ and ϕ of 0.5642 (18) Å, 177.32 (17) and ϕ = 10 (4)°, respectively. The two benzene rings make a dihedral angle of 42.67 (8)° with each other. An intra­molecular O—H⋯N hydrogen bond helps to stabilize the mol­ecular conformation. Aromatic C—H⋯π inter­actions and π–π stacking inter­actions [centroid–centroid distance = 3.6155 (15) Å] between the benzene rings contribute to the stabilization of the crystal structure. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050317/ /pubmed/21522655 http://dx.doi.org/10.1107/S1600536810052311 Text en © Akkurt et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Türktekin, Sevim
Jarrahpour, Aliasghar
Sharghi, Hashem
Badrabady, Seid Ali Torabi
Aberi, Mahdi
Büyükgüngör, Orhan
2-[(E)-(4-Methyl­phen­yl)imino­meth­yl]-6-(morpholin-4-ylmeth­yl)phenol
title 2-[(E)-(4-Methyl­phen­yl)imino­meth­yl]-6-(morpholin-4-ylmeth­yl)phenol
title_full 2-[(E)-(4-Methyl­phen­yl)imino­meth­yl]-6-(morpholin-4-ylmeth­yl)phenol
title_fullStr 2-[(E)-(4-Methyl­phen­yl)imino­meth­yl]-6-(morpholin-4-ylmeth­yl)phenol
title_full_unstemmed 2-[(E)-(4-Methyl­phen­yl)imino­meth­yl]-6-(morpholin-4-ylmeth­yl)phenol
title_short 2-[(E)-(4-Methyl­phen­yl)imino­meth­yl]-6-(morpholin-4-ylmeth­yl)phenol
title_sort 2-[(e)-(4-methyl­phen­yl)imino­meth­yl]-6-(morpholin-4-ylmeth­yl)phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050317/
https://www.ncbi.nlm.nih.gov/pubmed/21522655
http://dx.doi.org/10.1107/S1600536810052311
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