Diiodidobis(triphenyl­phosphine oxide)cadmium

In the title compound, [CdI(2){(C(6)H(5))(3)PO}(2)], the Cd(II) atom is ligated by two I atoms and two O atoms from two triphenyl­phosphine oxide ligands in a disorted tetra­hedral arrangement. While the O—Cd—I angles vary from 106.67 (7) to 111.23 (7)°, the O—Cd—O angle is 88.60 (10)° and the I—Cd—...

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Detalles Bibliográficos
Autores principales: Shanthakumari, R., Hema, R., Ramamurthy, K., Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050319/
https://www.ncbi.nlm.nih.gov/pubmed/21522527
http://dx.doi.org/10.1107/S160053681005302X
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author Shanthakumari, R.
Hema, R.
Ramamurthy, K.
Stoeckli-Evans, Helen
author_facet Shanthakumari, R.
Hema, R.
Ramamurthy, K.
Stoeckli-Evans, Helen
author_sort Shanthakumari, R.
collection PubMed
description In the title compound, [CdI(2){(C(6)H(5))(3)PO}(2)], the Cd(II) atom is ligated by two I atoms and two O atoms from two triphenyl­phosphine oxide ligands in a disorted tetra­hedral arrangement. While the O—Cd—I angles vary from 106.67 (7) to 111.23 (7)°, the O—Cd—O angle is 88.60 (10)° and the I—Cd—I angle angle is 125.47 (2)°. The crystal structure is stabilized by van der Waals forces only.
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spelling pubmed-30503192011-04-26 Diiodidobis(triphenyl­phosphine oxide)cadmium Shanthakumari, R. Hema, R. Ramamurthy, K. Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdI(2){(C(6)H(5))(3)PO}(2)], the Cd(II) atom is ligated by two I atoms and two O atoms from two triphenyl­phosphine oxide ligands in a disorted tetra­hedral arrangement. While the O—Cd—I angles vary from 106.67 (7) to 111.23 (7)°, the O—Cd—O angle is 88.60 (10)° and the I—Cd—I angle angle is 125.47 (2)°. The crystal structure is stabilized by van der Waals forces only. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050319/ /pubmed/21522527 http://dx.doi.org/10.1107/S160053681005302X Text en © Shanthakumari et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shanthakumari, R.
Hema, R.
Ramamurthy, K.
Stoeckli-Evans, Helen
Diiodidobis(triphenyl­phosphine oxide)cadmium
title Diiodidobis(triphenyl­phosphine oxide)cadmium
title_full Diiodidobis(triphenyl­phosphine oxide)cadmium
title_fullStr Diiodidobis(triphenyl­phosphine oxide)cadmium
title_full_unstemmed Diiodidobis(triphenyl­phosphine oxide)cadmium
title_short Diiodidobis(triphenyl­phosphine oxide)cadmium
title_sort diiodidobis(triphenyl­phosphine oxide)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050319/
https://www.ncbi.nlm.nih.gov/pubmed/21522527
http://dx.doi.org/10.1107/S160053681005302X
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AT hemar diiodidobistriphenylphosphineoxidecadmium
AT ramamurthyk diiodidobistriphenylphosphineoxidecadmium
AT stoecklievanshelen diiodidobistriphenylphosphineoxidecadmium

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