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{2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)copper(II)
In the title compound, [Cu(NCS)(2)(C(13)H(19)N(3)O)], the Cu(II) ion is five-coordinated by the N,N′,N′′-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C—H⋯N, C—H⋯O and C—H⋯S interactions link adjacent molecules into layers par...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050323/ https://www.ncbi.nlm.nih.gov/pubmed/21522576 http://dx.doi.org/10.1107/S1600536810050889 |
| _version_ | 1782199337140355072 |
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| author | Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
| author_facet | Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
| author_sort | Suleiman Gwaram, Nura |
| collection | PubMed |
| description | In the title compound, [Cu(NCS)(2)(C(13)H(19)N(3)O)], the Cu(II) ion is five-coordinated by the N,N′,N′′-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C—H⋯N, C—H⋯O and C—H⋯S interactions link adjacent molecules into layers parallel to the ac plane. A weak intermolecular π–π interaction occurs between the aromatic rings with a centroid–centroid distance of 3.9412 (9) Å. |
| format | Text |
| id | pubmed-3050323 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30503232011-04-26 {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)copper(II) Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NCS)(2)(C(13)H(19)N(3)O)], the Cu(II) ion is five-coordinated by the N,N′,N′′-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C—H⋯N, C—H⋯O and C—H⋯S interactions link adjacent molecules into layers parallel to the ac plane. A weak intermolecular π–π interaction occurs between the aromatic rings with a centroid–centroid distance of 3.9412 (9) Å. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050323/ /pubmed/21522576 http://dx.doi.org/10.1107/S1600536810050889 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)copper(II) |
| title | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
| title_full | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
| title_fullStr | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
| title_full_unstemmed | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
| title_short | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
| title_sort | {2-morpholino-n-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
n,n′,n′′}bis(thiocyanato-κn)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050323/ https://www.ncbi.nlm.nih.gov/pubmed/21522576 http://dx.doi.org/10.1107/S1600536810050889 |
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