Bromidotricarbon­yl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN (4)]rhenium(I) dichloro­methane monosolvate

In the title rhenium(I) complex, [ReBr(C(13)H(9)N(3)O)(CO)(3)]·CH(2)Cl(2), the dichloro­methane solvent mol­ecule is disordered over two positions with an occupancy ratio of 0.81 (15):0.19 (15). The Re(I) atom is coordinated by two N atoms from a 2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole (L) lig...

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Autores principales: Shi, Lin-Fang, Si, Zhen-Jun, Li, Yan-Wei, Cao, Hua-Ru, Guan, Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050326/
https://www.ncbi.nlm.nih.gov/pubmed/21522603
http://dx.doi.org/10.1107/S1600536810052360
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author Shi, Lin-Fang
Si, Zhen-Jun
Li, Yan-Wei
Cao, Hua-Ru
Guan, Ying
author_facet Shi, Lin-Fang
Si, Zhen-Jun
Li, Yan-Wei
Cao, Hua-Ru
Guan, Ying
author_sort Shi, Lin-Fang
collection PubMed
description In the title rhenium(I) complex, [ReBr(C(13)H(9)N(3)O)(CO)(3)]·CH(2)Cl(2), the dichloro­methane solvent mol­ecule is disordered over two positions with an occupancy ratio of 0.81 (15):0.19 (15). The Re(I) atom is coordinated by two N atoms from a 2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole (L) ligand, three C atoms from three carbonyl groups and a Br atom in a distorted octa­hedral geometry. The three rings in L are almost coplanar (a mean plane fitted through all non-H atoms of this ligand has an r.m.s. deviation of 0.063 Å), and the carbonyl ligands are coordinated in a fac arrangement.
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spelling pubmed-30503262011-04-26 Bromidotricarbon­yl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN (4)]rhenium(I) dichloro­methane monosolvate Shi, Lin-Fang Si, Zhen-Jun Li, Yan-Wei Cao, Hua-Ru Guan, Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title rhenium(I) complex, [ReBr(C(13)H(9)N(3)O)(CO)(3)]·CH(2)Cl(2), the dichloro­methane solvent mol­ecule is disordered over two positions with an occupancy ratio of 0.81 (15):0.19 (15). The Re(I) atom is coordinated by two N atoms from a 2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole (L) ligand, three C atoms from three carbonyl groups and a Br atom in a distorted octa­hedral geometry. The three rings in L are almost coplanar (a mean plane fitted through all non-H atoms of this ligand has an r.m.s. deviation of 0.063 Å), and the carbonyl ligands are coordinated in a fac arrangement. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050326/ /pubmed/21522603 http://dx.doi.org/10.1107/S1600536810052360 Text en © Shi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Lin-Fang
Si, Zhen-Jun
Li, Yan-Wei
Cao, Hua-Ru
Guan, Ying
Bromidotricarbon­yl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN (4)]rhenium(I) dichloro­methane monosolvate
title Bromidotricarbon­yl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN (4)]rhenium(I) dichloro­methane monosolvate
title_full Bromidotricarbon­yl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN (4)]rhenium(I) dichloro­methane monosolvate
title_fullStr Bromidotricarbon­yl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN (4)]rhenium(I) dichloro­methane monosolvate
title_full_unstemmed Bromidotricarbon­yl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN (4)]rhenium(I) dichloro­methane monosolvate
title_short Bromidotricarbon­yl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN (4)]rhenium(I) dichloro­methane monosolvate
title_sort bromidotricarbon­yl[2-phenyl-5-(pyridin-2-yl-κn)-1,3,4-oxadiazole-κn (4)]rhenium(i) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050326/
https://www.ncbi.nlm.nih.gov/pubmed/21522603
http://dx.doi.org/10.1107/S1600536810052360
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AT sizhenjun bromidotricarbonyl2phenyl5pyridin2ylkn134oxadiazolekn4rheniumidichloromethanemonosolvate
AT liyanwei bromidotricarbonyl2phenyl5pyridin2ylkn134oxadiazolekn4rheniumidichloromethanemonosolvate
AT caohuaru bromidotricarbonyl2phenyl5pyridin2ylkn134oxadiazolekn4rheniumidichloromethanemonosolvate
AT guanying bromidotricarbonyl2phenyl5pyridin2ylkn134oxadiazolekn4rheniumidichloromethanemonosolvate

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