Cargando…
Poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3) O:O′:O′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3) O,O′:O′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetrazinc(II)]
In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetrahedral geometry by two O atoms from benzene-1,3-dicarboxylate (BDC) ligands, one N atom from a 1,4-bis(1,2,4-triazol-1-yl)butane (...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050338/ https://www.ncbi.nlm.nih.gov/pubmed/21522591 http://dx.doi.org/10.1107/S1600536810051433 |
Sumario: | In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetrahedral geometry by two O atoms from benzene-1,3-dicarboxylate (BDC) ligands, one N atom from a 1,4-bis(1,2,4-triazol-1-yl)butane (BTB) ligand and one water molecule, while a second Zn(II) atom is five-coordinated in a distorted square-pyramidal geometry bridged by four O atoms from BDC ligands and one water molecule. The Zn(II) atoms are connected by the benzene-1,3-dicarboxylate anions and the nitrogen ligand into layers parallel to the ac plane. The asymmetric unit consits of two crystallographically independent Zn(II) cations, two BDC anions and two water molecules in general positions, as well as one-half of the BTB ligand that is completed by inversion symmetry. |
---|