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Poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3) O:O′:O′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3) O,O′:O′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetrazinc(II)]
In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetrahedral geometry by two O atoms from benzene-1,3-dicarboxylate (BDC) ligands, one N atom from a 1,4-bis(1,2,4-triazol-1-yl)butane (...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050338/ https://www.ncbi.nlm.nih.gov/pubmed/21522591 http://dx.doi.org/10.1107/S1600536810051433 |
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author | Fu, Gui-Hong |
author_facet | Fu, Gui-Hong |
author_sort | Fu, Gui-Hong |
collection | PubMed |
description | In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetrahedral geometry by two O atoms from benzene-1,3-dicarboxylate (BDC) ligands, one N atom from a 1,4-bis(1,2,4-triazol-1-yl)butane (BTB) ligand and one water molecule, while a second Zn(II) atom is five-coordinated in a distorted square-pyramidal geometry bridged by four O atoms from BDC ligands and one water molecule. The Zn(II) atoms are connected by the benzene-1,3-dicarboxylate anions and the nitrogen ligand into layers parallel to the ac plane. The asymmetric unit consits of two crystallographically independent Zn(II) cations, two BDC anions and two water molecules in general positions, as well as one-half of the BTB ligand that is completed by inversion symmetry. |
format | Text |
id | pubmed-3050338 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30503382011-04-26 Poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3) O:O′:O′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3) O,O′:O′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetrazinc(II)] Fu, Gui-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetrahedral geometry by two O atoms from benzene-1,3-dicarboxylate (BDC) ligands, one N atom from a 1,4-bis(1,2,4-triazol-1-yl)butane (BTB) ligand and one water molecule, while a second Zn(II) atom is five-coordinated in a distorted square-pyramidal geometry bridged by four O atoms from BDC ligands and one water molecule. The Zn(II) atoms are connected by the benzene-1,3-dicarboxylate anions and the nitrogen ligand into layers parallel to the ac plane. The asymmetric unit consits of two crystallographically independent Zn(II) cations, two BDC anions and two water molecules in general positions, as well as one-half of the BTB ligand that is completed by inversion symmetry. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050338/ /pubmed/21522591 http://dx.doi.org/10.1107/S1600536810051433 Text en © Gui-Hong Fu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fu, Gui-Hong Poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3) O:O′:O′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3) O,O′:O′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetrazinc(II)] |
title | Poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3)
O:O′:O′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3)
O,O′:O′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N:N′]tetrazinc(II)] |
title_full | Poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3)
O:O′:O′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3)
O,O′:O′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N:N′]tetrazinc(II)] |
title_fullStr | Poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3)
O:O′:O′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3)
O,O′:O′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N:N′]tetrazinc(II)] |
title_full_unstemmed | Poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3)
O:O′:O′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3)
O,O′:O′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N:N′]tetrazinc(II)] |
title_short | Poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3)
O:O′:O′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3)
O,O′:O′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N:N′]tetrazinc(II)] |
title_sort | poly[tetraaquabis(μ(3)-benzene-1,3-dicarboxylato-κ(3)
o:o′:o′′)bis(μ(2)-benzene-1,3-dicarboxylato-κ(3)
o,o′:o′′)[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
n:n′]tetrazinc(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050338/ https://www.ncbi.nlm.nih.gov/pubmed/21522591 http://dx.doi.org/10.1107/S1600536810051433 |
work_keys_str_mv | AT fuguihong polytetraaquabism3benzene13dicarboxylatok3ooobism2benzene13dicarboxylatok3ooom214bis124triazol1ylbutanek2nntetrazincii |