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Poly[tetra­aqua­bis­(μ(3)-benzene-1,3-di­carboxyl­ato-κ(3) O:O′:O′′)bis­(μ(2)-benzene-1,3-dicarboxyl­ato-κ(3) O,O′:O′′)[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetra­zinc(II)]

In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetra­hedral geometry by two O atoms from benzene-1,3-dicarboxyl­ate (BDC) ligands, one N atom from a 1,4-bis­(1,2,4-triazol-1-yl)butane (...

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Detalles Bibliográficos
Autor principal: Fu, Gui-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050338/
https://www.ncbi.nlm.nih.gov/pubmed/21522591
http://dx.doi.org/10.1107/S1600536810051433
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author Fu, Gui-Hong
author_facet Fu, Gui-Hong
author_sort Fu, Gui-Hong
collection PubMed
description In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetra­hedral geometry by two O atoms from benzene-1,3-dicarboxyl­ate (BDC) ligands, one N atom from a 1,4-bis­(1,2,4-triazol-1-yl)butane (BTB) ligand and one water mol­ecule, while a second Zn(II) atom is five-coordinated in a distorted square-pyramidal geometry bridged by four O atoms from BDC ligands and one water mol­ecule. The Zn(II) atoms are connected by the benzene-1,3-dicarboxyl­ate anions and the nitro­gen ligand into layers parallel to the ac plane. The asymmetric unit consits of two crystallographically independent Zn(II) cations, two BDC anions and two water mol­ecules in general positions, as well as one-half of the BTB ligand that is completed by inversion symmetry.
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spelling pubmed-30503382011-04-26 Poly[tetra­aqua­bis­(μ(3)-benzene-1,3-di­carboxyl­ato-κ(3) O:O′:O′′)bis­(μ(2)-benzene-1,3-dicarboxyl­ato-κ(3) O,O′:O′′)[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetra­zinc(II)] Fu, Gui-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetra­hedral geometry by two O atoms from benzene-1,3-dicarboxyl­ate (BDC) ligands, one N atom from a 1,4-bis­(1,2,4-triazol-1-yl)butane (BTB) ligand and one water mol­ecule, while a second Zn(II) atom is five-coordinated in a distorted square-pyramidal geometry bridged by four O atoms from BDC ligands and one water mol­ecule. The Zn(II) atoms are connected by the benzene-1,3-dicarboxyl­ate anions and the nitro­gen ligand into layers parallel to the ac plane. The asymmetric unit consits of two crystallographically independent Zn(II) cations, two BDC anions and two water mol­ecules in general positions, as well as one-half of the BTB ligand that is completed by inversion symmetry. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050338/ /pubmed/21522591 http://dx.doi.org/10.1107/S1600536810051433 Text en © Gui-Hong Fu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fu, Gui-Hong
Poly[tetra­aqua­bis­(μ(3)-benzene-1,3-di­carboxyl­ato-κ(3) O:O′:O′′)bis­(μ(2)-benzene-1,3-dicarboxyl­ato-κ(3) O,O′:O′′)[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetra­zinc(II)]
title Poly[tetra­aqua­bis­(μ(3)-benzene-1,3-di­carboxyl­ato-κ(3) O:O′:O′′)bis­(μ(2)-benzene-1,3-dicarboxyl­ato-κ(3) O,O′:O′′)[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetra­zinc(II)]
title_full Poly[tetra­aqua­bis­(μ(3)-benzene-1,3-di­carboxyl­ato-κ(3) O:O′:O′′)bis­(μ(2)-benzene-1,3-dicarboxyl­ato-κ(3) O,O′:O′′)[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetra­zinc(II)]
title_fullStr Poly[tetra­aqua­bis­(μ(3)-benzene-1,3-di­carboxyl­ato-κ(3) O:O′:O′′)bis­(μ(2)-benzene-1,3-dicarboxyl­ato-κ(3) O,O′:O′′)[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetra­zinc(II)]
title_full_unstemmed Poly[tetra­aqua­bis­(μ(3)-benzene-1,3-di­carboxyl­ato-κ(3) O:O′:O′′)bis­(μ(2)-benzene-1,3-dicarboxyl­ato-κ(3) O,O′:O′′)[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetra­zinc(II)]
title_short Poly[tetra­aqua­bis­(μ(3)-benzene-1,3-di­carboxyl­ato-κ(3) O:O′:O′′)bis­(μ(2)-benzene-1,3-dicarboxyl­ato-κ(3) O,O′:O′′)[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N:N′]tetra­zinc(II)]
title_sort poly[tetra­aqua­bis­(μ(3)-benzene-1,3-di­carboxyl­ato-κ(3) o:o′:o′′)bis­(μ(2)-benzene-1,3-dicarboxyl­ato-κ(3) o,o′:o′′)[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) n:n′]tetra­zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050338/
https://www.ncbi.nlm.nih.gov/pubmed/21522591
http://dx.doi.org/10.1107/S1600536810051433
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