Bis{N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline-κ(2) P,P′}copper(I) tetra­fluoridoborate

In the cation of the title compound, [Cu(C(32)H(29)NP(2))(2)]BF(4), the Cu(I) atom is four-coordinated in a distorted tetra­hedral geometry by four P atoms from two N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline ligands. In the crystal, the cations are linked by C—H⋯π inter­actions, forming chains a...

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Detalles Bibliográficos
Autores principales: Shang, Jing, Huang, Li-Li, Huang, Ting-Hong, Ma, Kai, Ni, Qing-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050340/
https://www.ncbi.nlm.nih.gov/pubmed/21522609
http://dx.doi.org/10.1107/S160053681005186X
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author Shang, Jing
Huang, Li-Li
Huang, Ting-Hong
Ma, Kai
Ni, Qing-Ling
author_facet Shang, Jing
Huang, Li-Li
Huang, Ting-Hong
Ma, Kai
Ni, Qing-Ling
author_sort Shang, Jing
collection PubMed
description In the cation of the title compound, [Cu(C(32)H(29)NP(2))(2)]BF(4), the Cu(I) atom is four-coordinated in a distorted tetra­hedral geometry by four P atoms from two N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline ligands. In the crystal, the cations are linked by C—H⋯π inter­actions, forming chains along the a axis. Intra­molecular C—H⋯N and inter­molecular C—H⋯F hydrogen bonds are also observed.
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spelling pubmed-30503402011-04-26 Bis{N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline-κ(2) P,P′}copper(I) tetra­fluoridoborate Shang, Jing Huang, Li-Li Huang, Ting-Hong Ma, Kai Ni, Qing-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Cu(C(32)H(29)NP(2))(2)]BF(4), the Cu(I) atom is four-coordinated in a distorted tetra­hedral geometry by four P atoms from two N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline ligands. In the crystal, the cations are linked by C—H⋯π inter­actions, forming chains along the a axis. Intra­molecular C—H⋯N and inter­molecular C—H⋯F hydrogen bonds are also observed. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050340/ /pubmed/21522609 http://dx.doi.org/10.1107/S160053681005186X Text en © Shang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shang, Jing
Huang, Li-Li
Huang, Ting-Hong
Ma, Kai
Ni, Qing-Ling
Bis{N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline-κ(2) P,P′}copper(I) tetra­fluoridoborate
title Bis{N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline-κ(2) P,P′}copper(I) tetra­fluoridoborate
title_full Bis{N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline-κ(2) P,P′}copper(I) tetra­fluoridoborate
title_fullStr Bis{N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline-κ(2) P,P′}copper(I) tetra­fluoridoborate
title_full_unstemmed Bis{N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline-κ(2) P,P′}copper(I) tetra­fluoridoborate
title_short Bis{N,N-bis­[(diphenyl­phosphan­yl)meth­yl]aniline-κ(2) P,P′}copper(I) tetra­fluoridoborate
title_sort bis{n,n-bis­[(diphenyl­phosphan­yl)meth­yl]aniline-κ(2) p,p′}copper(i) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050340/
https://www.ncbi.nlm.nih.gov/pubmed/21522609
http://dx.doi.org/10.1107/S160053681005186X
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