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[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis(thiocyanato-κN)cadmium(II)
In the title complex, [Cd(NCS)(2)(C(22)H(20)N(6))], the Cd(II) ion is in a CdN(6) coordination geometry which is intermediate between octahedral and trigonal–prismatic. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050342/ https://www.ncbi.nlm.nih.gov/pubmed/21522586 http://dx.doi.org/10.1107/S1600536810051275 |
| _version_ | 1782199341642940416 |
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| author | Zheng, Lu Yi Chi, Yan Hui |
| author_facet | Zheng, Lu Yi Chi, Yan Hui |
| author_sort | Zheng, Lu Yi |
| collection | PubMed |
| description | In the title complex, [Cd(NCS)(2)(C(22)H(20)N(6))], the Cd(II) ion is in a CdN(6) coordination geometry which is intermediate between octahedral and trigonal–prismatic. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (13)°. In the crystal, there is a π–π stacking interaction involving two symmetry-related pyrazole rings, with a centroid–centroid distance of 3.664 (3) Å. In addition, there is a relatively short intermolecular contact between C atoms [C⋯C = 3.399 (6) Å] involving symmetry-related pyridine rings along the a axis. |
| format | Text |
| id | pubmed-3050342 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30503422011-04-26 [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis(thiocyanato-κN)cadmium(II) Zheng, Lu Yi Chi, Yan Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(NCS)(2)(C(22)H(20)N(6))], the Cd(II) ion is in a CdN(6) coordination geometry which is intermediate between octahedral and trigonal–prismatic. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (13)°. In the crystal, there is a π–π stacking interaction involving two symmetry-related pyrazole rings, with a centroid–centroid distance of 3.664 (3) Å. In addition, there is a relatively short intermolecular contact between C atoms [C⋯C = 3.399 (6) Å] involving symmetry-related pyridine rings along the a axis. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050342/ /pubmed/21522586 http://dx.doi.org/10.1107/S1600536810051275 Text en © Zheng and Chi 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zheng, Lu Yi Chi, Yan Hui [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis(thiocyanato-κN)cadmium(II) |
| title | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(thiocyanato-κN)cadmium(II) |
| title_full | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(thiocyanato-κN)cadmium(II) |
| title_fullStr | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(thiocyanato-κN)cadmium(II) |
| title_full_unstemmed | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(thiocyanato-κN)cadmium(II) |
| title_short | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(thiocyanato-κN)cadmium(II) |
| title_sort | [2,9-bis(3,5-dimethyl-1h-pyrazol-1-yl-κn
(2))-1,10-phenanthroline-κ(2)
n,n′]bis(thiocyanato-κn)cadmium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050342/ https://www.ncbi.nlm.nih.gov/pubmed/21522586 http://dx.doi.org/10.1107/S1600536810051275 |
| work_keys_str_mv | AT zhengluyi 29bis35dimethyl1hpyrazol1ylkn2110phenanthrolinek2nnbisthiocyanatokncadmiumii AT chiyanhui 29bis35dimethyl1hpyrazol1ylkn2110phenanthrolinek2nnbisthiocyanatokncadmiumii |