Hexaaqua­magnesium dibromide 5-(pyridinium-3-yl)tetra­zol-1-ide

In the title compound, [Mg(H(2)O)(6)]Br(2)·2C(6)H(5)N(5), the Mg(II) atom, lying on an inversion center, is coordinated by six water mol­ecules in a distorted octa­hedral geometry. The pyridine and tetra­zole rings in the 5-(pyridinium-3-yl)tetra­zol-1-ide zwitterion are nearly coplanar, twisted fro...

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Detalles Bibliográficos
Autores principales: Dai, Jing, Chen, Xin-Yuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050346/
https://www.ncbi.nlm.nih.gov/pubmed/21522526
http://dx.doi.org/10.1107/S1600536810052992
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author Dai, Jing
Chen, Xin-Yuan
author_facet Dai, Jing
Chen, Xin-Yuan
author_sort Dai, Jing
collection PubMed
description In the title compound, [Mg(H(2)O)(6)]Br(2)·2C(6)H(5)N(5), the Mg(II) atom, lying on an inversion center, is coordinated by six water mol­ecules in a distorted octa­hedral geometry. The pyridine and tetra­zole rings in the 5-(pyridinium-3-yl)tetra­zol-1-ide zwitterion are nearly coplanar, twisted from each other by a dihedral angle of 5.70 (1)°. The zwitterions, Br anions and complex cations are connected by O—H⋯Br, O—H⋯N and N—H⋯Br hydrogen bonds, leading to the formation of a three-dimensional network.
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spelling pubmed-30503462011-04-26 Hexaaqua­magnesium dibromide 5-(pyridinium-3-yl)tetra­zol-1-ide Dai, Jing Chen, Xin-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mg(H(2)O)(6)]Br(2)·2C(6)H(5)N(5), the Mg(II) atom, lying on an inversion center, is coordinated by six water mol­ecules in a distorted octa­hedral geometry. The pyridine and tetra­zole rings in the 5-(pyridinium-3-yl)tetra­zol-1-ide zwitterion are nearly coplanar, twisted from each other by a dihedral angle of 5.70 (1)°. The zwitterions, Br anions and complex cations are connected by O—H⋯Br, O—H⋯N and N—H⋯Br hydrogen bonds, leading to the formation of a three-dimensional network. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050346/ /pubmed/21522526 http://dx.doi.org/10.1107/S1600536810052992 Text en © Dai and Chen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dai, Jing
Chen, Xin-Yuan
Hexaaqua­magnesium dibromide 5-(pyridinium-3-yl)tetra­zol-1-ide
title Hexaaqua­magnesium dibromide 5-(pyridinium-3-yl)tetra­zol-1-ide
title_full Hexaaqua­magnesium dibromide 5-(pyridinium-3-yl)tetra­zol-1-ide
title_fullStr Hexaaqua­magnesium dibromide 5-(pyridinium-3-yl)tetra­zol-1-ide
title_full_unstemmed Hexaaqua­magnesium dibromide 5-(pyridinium-3-yl)tetra­zol-1-ide
title_short Hexaaqua­magnesium dibromide 5-(pyridinium-3-yl)tetra­zol-1-ide
title_sort hexaaqua­magnesium dibromide 5-(pyridinium-3-yl)tetra­zol-1-ide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050346/
https://www.ncbi.nlm.nih.gov/pubmed/21522526
http://dx.doi.org/10.1107/S1600536810052992
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AT chenxinyuan hexaaquamagnesiumdibromide5pyridinium3yltetrazol1ide

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