N-(3,4-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide

In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N—C bond in the C—SO(2)—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of 64.3 (4)°. Furthermore, the conformation of the N—H bond and the meta...

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Detalles Bibliográficos
Autores principales: Shakuntala, K., Foro, Sabine, Gowda, B. Thimme
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050347/
https://www.ncbi.nlm.nih.gov/pubmed/21522617
http://dx.doi.org/10.1107/S1600536810051305
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author Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
author_facet Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
author_sort Shakuntala, K.
collection PubMed
description In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N—C bond in the C—SO(2)—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of 64.3 (4)°. Furthermore, the conformation of the N—H bond and the meta-chloro group in the adjacent benzene ring are anti to each other. The two benzene rings are tilted relative to each other by 82.5 (1)°. In the crystal, mol­ecules are linked by pairs of N—H⋯O(S) hydrogen bonds, forming inversion dimers.
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spelling pubmed-30503472011-04-26 N-(3,4-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide Shakuntala, K. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N—C bond in the C—SO(2)—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of 64.3 (4)°. Furthermore, the conformation of the N—H bond and the meta-chloro group in the adjacent benzene ring are anti to each other. The two benzene rings are tilted relative to each other by 82.5 (1)°. In the crystal, mol­ecules are linked by pairs of N—H⋯O(S) hydrogen bonds, forming inversion dimers. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050347/ /pubmed/21522617 http://dx.doi.org/10.1107/S1600536810051305 Text en © Shakuntala et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
N-(3,4-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title N-(3,4-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_full N-(3,4-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_fullStr N-(3,4-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_full_unstemmed N-(3,4-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_short N-(3,4-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_sort n-(3,4-dichloro­phen­yl)-4-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050347/
https://www.ncbi.nlm.nih.gov/pubmed/21522617
http://dx.doi.org/10.1107/S1600536810051305
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